Issue 68, 2016
From the journal:

Chemical Communications

Visible-light induced oxidant-free oxidative cross-coupling for constructing allylic sulfones from olefins and sulfinic acids†

Guoting Zhang,a   Lingling Zhang,a   Hong Yi,a   Yi Luo,a   Xiaotian Qi,b   Chen-Ho Tung,c   Li-Zhu Wu*c  and  Aiwen Lei*ad  

* Corresponding authors

a College of Chemistry and Molecular Sciences, the Institute for Advanced Studies (IAS), Wuhan University, Wuhan, P. R. China
E-mail: aiwenlei@whu.edu.cn

b School of Chemistry and Chemical Engineering, Chongqing University, Chongqing 400030, P. R. China

c Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry & University of Chinese Academy of Sciences, Chinese Academy of Sciences, Beijing 100190, P. R. China
E-mail: lzwu@mail.ipc.ac.cn

d Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, P. R. China

Abstract

An oxidant-free dehydrogenative sulfonylation of α-methyl-styrene derivatives was developed for the construction of allylic sulfones by using eosin Y as a photosensitizer in conjunction with a cobaloxime catalyst. The process features a low-cost metal catalyst and atom economy, which provides an appealing strategy for future synthetic chemistry.

Graphical abstract: Visible-light induced oxidant-free oxidative cross-coupling for constructing allylic sulfones from olefins and sulfinic acids

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Article information

DOI
https://doi.org/10.1039/C6CC04109D
Article type
Communication
Submitted
16 May 2016
Accepted
18 Jul 2016
First published
18 Jul 2016

Chem. Commun., 2016,52, 10407-10410

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Visible-light induced oxidant-free oxidative cross-coupling for constructing allylic sulfones from olefins and sulfinic acids

G. Zhang, L. Zhang, H. Yi, Y. Luo, X. Qi, C. Tung, L. Wu and A. Lei, Chem. Commun., 2016, 52, 10407 DOI: 10.1039/C6CC04109D

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