Issue 37, 2016
From the journal:

Dalton Transactions

Divergent reactivity of platinum(ii) and palladium(ii) methylperoxo complexes and the formation of an unusual hemi-aminal complex†

Allan R. Petersen,a   Andrew J. P. Whitea  and  George J. P. Britovsek*a  

* Corresponding authors

a Department of Chemistry, Imperial College London, Exhibition Road, London, UK
E-mail: g.britovsek@imperial.ac.uk
Fax: +44(0) 20-75945804
Tel: +44(0) 20-75945863

Abstract

The 6,6′′-diaminoterpyridine palladium(II) methylperoxo complex eliminates methyl hydroperoxide and reacts with acetone to form a novel hemi-aminal palladium complex, whereas the analogous platinum(II) complex generates formaldehyde and a platinum(II) hydroxo complex.

Graphical abstract: Divergent reactivity of platinum(ii) and palladium(ii) methylperoxo complexes and the formation of an unusual hemi-aminal complex

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C6DT01691J
Article type
Communication
Submitted
29 Apr 2016
Accepted
27 May 2016
First published
30 May 2016

Dalton Trans., 2016,45, 14520-14523

Permissions

Request permissions

Divergent reactivity of platinum(II) and palladium(II) methylperoxo complexes and the formation of an unusual hemi-aminal complex

A. R. Petersen, A. J. P. White and G. J. P. Britovsek, Dalton Trans., 2016, 45, 14520 DOI: 10.1039/C6DT01691J

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements