Issue 17, 2017
From the journal:

Chemical Communications

[V4Mo3O14(NAr)3(μ2-NAr)3]2−: the first polyarylimido-stabilized molybdovanadate cluster†

Yichao Huang,abc   Jiangwei Zhang, ORCID logo a   Jingxuan Ge,a   Chong Sui,a   Jian Hao*b  and  Yongge Wei*ac  

* Corresponding authors

a Key Lab of Organic Optoelectronics & Molecular Engineering of Ministry of Education, Department of Chemistry, Tsinghua University, Beijing 100084, P. R. China
E-mail: yonggewei@mail.tsinghua.edu.cn

b Analysis and Test Center, Beijing University of Chemical Technology, Beijing 100029, P. R. China
E-mail: xhaojian@163.com

c State Key Laboratory of Natural and Biomimetic Drugs, Peking University, Beijing 100191, P. R. China

Abstract

The first molybdovanadate cluster with a polyarylimido trimetal fragment, [V4Mo3O14(NAr)3(μ2-NAr)3]2−, was in situ synthesized by using (TBA)3[H3V10O28] as proton and vanadium sources. Additional aniline hydrochlorides will give rise to the formation of phenyl guanidines, which will serve as cations and proton donors to form chain-like and dimeric supermolecules via H-bonding.

Graphical abstract: [V4Mo3O14(NAr)3(μ2-NAr)3]2−: the first polyarylimido-stabilized molybdovanadate cluster

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Article information

DOI
https://doi.org/10.1039/C7CC00166E
Article type
Communication
Submitted
09 Jan 2017
Accepted
20 Jan 2017
First published
20 Jan 2017

Chem. Commun., 2017,53, 2551-2554

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[V4Mo3O14(NAr)3(μ2-NAr)3]2−: the first polyarylimido-stabilized molybdovanadate cluster

Y. Huang, J. Zhang, J. Ge, C. Sui, J. Hao and Y. Wei, Chem. Commun., 2017, 53, 2551 DOI: 10.1039/C7CC00166E

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