Pei-Yang
Gu‡
a,
Zilong
Wang‡
a,
Fang-Xing
Xiao
b,
Zongqiong
Lin
a,
Rongbin
Song
a,
Qing-Feng
Xu
c,
Jian-Mei
Lu
*c,
Bin
Liu
*b and
Qichun
Zhang
*ad
aSchool of Materials Science and Engineering, Nanyang Technological University, Singapore 639798, Singapore. E-mail: qczhang@ntu.edu.sg
bSchool of Chemical and Biomedical Engineering, Nanyang Technological University, Singapore 637459, Singapore. E-mail: liubin@ntu.edu.sg
cCollege of Chemistry, Chemical Engineering and Materials Science, Collaborative Innovation Center of Suzhou Nano Science and Technology, Soochow University, Suzhou 215123, P. R. China. E-mail: lujm@suda.edu.cn
dDivision of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore 637371, Singapore
First published on 23rd August 2016
Present photoelectrochemical (PEC) cells for water splitting are based on inorganic electrodes. For future large-scale applications, electrodes that are metal-free, of low cost, and with sustainable availability are crucial. Herein, we report a new ambipolar larger azaacene (DQNDN) as a single-active-element-based photocathode in PEC cells with a current density of 0.13 mA cm−2 at −0.13 V versus RHE.
As the counterpart of inorganic semiconductors, organic conjugated materials have been widely employed as active elements in optoelectronic devices such as solar cells,24,25 light-emitting diodes,26,27 field-effect transistors,28,29 and memory devices.30,31 However, their application as photoelectrodes in metal-free PEC cells is rare.32,33 Until now, only a few polymers (BBL) (poly(benzimidazobenzophenanthroline)34 and carbon nitride35,36) and some small molecules (porphyrins, perylenediimides or their hybrids37) have been demonstrated as promising photoelectrodes in PEC cells. Employing ambipolar conjugated molecules as single active elements in photocathodes for light-driven metal-free water reduction is unprecedented. More importantly, compared with polymer-based photoelectrodes, small molecules could offer several advantages including monodispersity, reliable synthetic reproducibility, and adjustable structure packing features.
We and other groups have demonstrated that azaacenes can be employed as promising organic semiconductors for many applications38,39 and their charge transport properties can range from p-, ambipolar, to n-type.40–42 Considering the balance of dynamic charge transport during PEC processing, ambipolar azaacenes could be good candidates for photoelectrodes. In this report, we successfully synthesized a new azaacene 6,11,18,23-tetrakis((triisopropylsilyl)ethynyl)diquinoxalino[g,g′]naphtha[1′′,8′′:3,4,5;4′′,5′′:3′,4′,5′]-dicyclopenta[1,2-b:1′,2′-b′]diquinoxaline (DQNDN, Scheme 1), which has been confirmed to show ambipolar transport properties through Mott–Schottky measurements. We believe that the as-prepared azaacene may possess the following advantages: (1) DQNDN may display strong absorption in the visible region due to its large planarity and longer conjugation length; (2) DQNDN may exhibit efficient charge separation and transport properties because large azaacenes usually possess good electron mobility; and (3) DQNDN may possess suitable reduction and oxidation potentials for water splitting. These favourable facts strongly encouraged us to investigate DQNDN as a potential photocathode in PEC cells.
The synthetic route to prepare DQNDN is shown in Scheme 1 and the detailed synthesis can be found in the ESI.† The intermediate compounds 1 and 2 were prepared according to literature procedures.43,44DQNDN was obtained as a brown-black powder in 68% yield through a one-step condensation reaction between 1 and 2 using acetic acid/chloroform as a mixed solvent. Although four triisopropylsilyl (TIPS) groups have been introduced to attach onto the backbone, the solubility of DQNDN is still poor and it is insoluble in common solvents. It can only dissolve in trifluoroacetic acid (TFA) owing to the protonation of nitrogen atoms. The thermal stability of DQNDN was evaluated by thermogravimetric analysis under a nitrogen atmosphere. As shown in Fig. S4 (ESI†), DQNDN displays very good thermal stability with an onset decomposition temperature of ∼405 °C (considering the 5% weight-loss temperature).
The nanostructured DQNDN was fabricated by slowly dropping ethanol into DQNDN/TFA solution with rapid stirring. The as-prepared precipitation was centrifuged and washed with ethanol, deionized water, and ethanol, respectively. Scanning electron microscopy analysis (SEM, Fig. 1) reveals that nanofibers (diameter: 100–200 nm) can evenly coat on the surface of fluorine-doped tin oxide (FTO) glass. The normalized solid-state absorption spectrum of the nanostructured DQNDN film is shown in Fig. S5 (ESI†), which possesses typical azaacene finger peaks (280, 360, 585 nm). The peak at 850 nm might come from its aggregation.45 Overall, the solid-state absorption spectrum of the nanostructured DQNDN film covers the whole visible spectrum region, suggesting that it should be a good light-absorbing material, which might be a good candidate for photoelectrodes in PEC cells.
Fig. 1 SEM images of nanostructured DQNDN nanofibers. At (a) low resolution and (b) high resolution. |
As shown in Fig. 2a, the PEC behaviour of DQNDN was measured under a 300 W xenon lamp (Newport) coupled to an AM 1.5 G filter in a three-electrode electrochemical system with a Ag/AgCl electrode as a reference, a Pt plate as a counter electrode, and the nanostructured DQNDN film as a working electrode. A 0.5 M Na2SO4 aqueous solution was used as the electrolyte. In our previous research, azaacenes have already been demonstrated as photoanodes in PEC cells.46,47 As a new member of the azaacene family, DQNDN was also tested as a photoanode in PEC cells. The linear scan voltammetry (LSV, Fig. 2b) and the corresponding current density–potential curves (Fig. S7a, ESI†) in the dark and under light irradiation display the largest current density of 0.81 μA cm−2 at 0.87 V versus the reversible hydrogen electrode (RHE), supporting the occurrence of PEC reactions. To confirm the real performance of the PEC cells based on the nanostructured DQNDN film, the time course of the photocurrent density was measured at a potential of 1.23 V versus the RHE, shown in Fig. S7b (ESI†). At the beginning, a fast current density decay was found, followed by a slight current density decrease, suggesting that the charge transfer and extraction are not optimal (the adjustment of PEC cell components may further improve the performance). The time course of the photocurrent density (∼30 nA cm−2) has also been measured at a potential of 0.61 V versus the RHE (Fig. S8, ESI†) for comparison with our previous work,46,47 and these results are similar. To further reveal the charge transport behaviour of the nanostructured DQNDN film, Mott–Schottky measurements were performed in 0.5 M Na2SO4 aqueous solution. As shown in Fig. S9 (ESI†), the positive slope displays the n-type behaviour of the nanostructured DQNDN film, which is consistent with our previous PEC analysis.46,47 Besides the n-type behaviour, the Mott–Schottky measurement also provides us with a negative slope (p-type behaviour), suggesting that the nanostructured DQNDN film could also be utilized as a photocathode in PEC cells.
As shown in Fig. 3a and b, the LSV and the corresponding current density–potential curve exhibit the largest current density of 0.13 mA cm−2 at −0.13 V versus RHE, indicating that the nanostructured DQNDN film can be used as a good photocathode in PEC cells. To further understand the photocathode behaviours of the nanostructured DQNDN film, the time course of the photocurrent density was measured at a potential of −0.20 V versus RHE in Fig. 3c. The photocurrent density closely matches that of the LSV curve and exhibits almost no change over repeated cycles with stability for at least 12 h, which clearly suggests that the nanostructured DQNDN film is stable as a photocathode and unstable as a photoanode.
We also carried out electrochemical impedance spectroscopy (EIS) measurements of DQNDN at −0.20 V versus RHE (this condition is similar to the photocurrent measurements) to characterize the charge transport properties between the photoelectrode and the electrolyte. The as-obtained results are presented as Nyquist plots in Fig. 3d, where the x- and y-axes are the real part (Z′) and the negative of the imaginary part (−Z′′) of the impedance. Compared with the result attained under dark conditions, the diameter of the semicircle in the Nyquist plots decreases under light irradiation, indicating that the charge transport resistance of the nanostructured DQNDN film at the interface domain of the electrode is remarkably decreased under light irradiation than that in the dark, which is in agreement with the increase of the photocurrent upon light irradiation.
Footnotes |
† Electronic supplementary information (ESI) available: Experimental procedures, synthesis of DQNDN, and fabrication and measurement of PEC cells. See DOI: 10.1039/c6qm00113k |
‡ Dr P.-Y. Gu and Z. Wang contributed equally to this work. |
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