Issue 8, 2018
From the journal:

Chemical Communications

Indications of magnetic coupling effects in spin cross-over molecular thin films†

Xin Zhang,‡*a   Alpha T. N'Diaye, ORCID logo *b   Xuanyuan Jiang,a   Xiaozhe Zhang,a   Yuewei Yin,a   Xuegang Chen,a   Xia Hong, ORCID logo *a   Xiaoshan Xu ORCID logo *a  and  Peter A. Dowben ORCID logo *a  

* Corresponding authors

a Department of Physics and Astronomy, University of Nebraska, Theodore Jorgensen Hall, 855 North 16th Street, U. Nebraska-Lincoln, Lincoln, Nebraska 68588-0299, USA
E-mail: pdowben1@unl.edu
Fax: +1-402-472-6148
Tel: +1-402-472-9838

b Advanced Light Source, Lawrence Berkeley National Laboratory, Berkeley, CA, USA

Abstract

Room temperature isothermal reversible spin crossover switching of [Fe(H2B(pz)2)2(bipy)] thin films is demonstrated. The magnetic oxide substrate locks the [Fe{H2B(pz)2}2(bipy)] largely in a low spin state. With an X-ray fluence, excitation to a high spin state occurs, while relaxation back to low spin state is aided by alternating the substrate magnetization.

Graphical abstract: Indications of magnetic coupling effects in spin cross-over molecular thin films

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Article information

DOI
https://doi.org/10.1039/C7CC08246K
Article type
Communication
Submitted
25 Oct 2017
Accepted
27 Dec 2017
First published
02 Jan 2018

Chem. Commun., 2018,54, 944-947

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Indications of magnetic coupling effects in spin cross-over molecular thin films

X. Zhang, A. T. N'Diaye, X. Jiang, X. Zhang, Y. Yin, X. Chen, X. Hong, X. Xu and P. A. Dowben, Chem. Commun., 2018, 54, 944 DOI: 10.1039/C7CC08246K

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