Issue 84, 2018

Self-assembly of a Si-based cage by the formation of 24 equivalent covalent bonds

Abstract

A robust, nano-sized covalent cage, of composition, [(PhSi)6(ctc)4]6− (H6ctc = cyclotricatechylene) has been prepared in a simple reaction in good yield. The tetrahedral anionic cage is stable in both the solid and solution state and exhibits an affinity for Cs+ ions which bind to the internal surface of the cage.

Graphical abstract: Self-assembly of a Si-based cage by the formation of 24 equivalent covalent bonds

Supplementary files

Article information

Article type
Communication
Submitted
06 Aug 2018
Accepted
26 Sep 2018
First published
04 Oct 2018

Chem. Commun., 2018,54, 11877-11880

Self-assembly of a Si-based cage by the formation of 24 equivalent covalent bonds

J. L. Holmes, B. F. Abrahams, A. Ahveninen, B. A. Boughton, T. A. Hudson, R. Robson and D. Thinagaran, Chem. Commun., 2018, 54, 11877 DOI: 10.1039/C8CC06405A

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