D. R.
Vinayakumara
a,
Hidayath
Ulla‡
b,
Sandeep
Kumar
c,
M. N.
Satyanarayan
d and
Airody Vasudeva
Adhikari
*a
aOrganic Materials Laboratory, Department of Chemistry, National Institute of Technology Karnataka, Surathkal, Mangalore-575 025, India. E-mail: avachem@gmail.com; avachem@nitk.ac.in
bDepartment of Chemistry, Indian Institute of Technology Guwahati, Guwahati-781 039, India
cSCM Group, Raman Research Institute, C.V. Raman Avenue, Sadashivanagar, Bangalore-560 080, India
dDepartment of Physics, National Institute of Technology Karnataka, Surathkal, Mangalore-575 025, India
First published on 8th October 2018
We report the design, synthesis, and self-assembly of a novel series of pseudodiscoid dyads comprising electron-rich dialkoxyphenanthrene and trialkoxyphenyl rings appended to an electron-deficient cyanopyridone core. Evidently, all the members of the series exhibited bi-mesophases with prospective columnar mesomorphism; moreover, it was steady under ambient conditions. The electro-optical studies revealed that the new liquid crystalline materials were efficient green light emitters both in solution and LC states with substantial chromaticity. Further, their theoretical studies (DFT) revealed that the molecules possess good intramolecular charge transport behavior. These superior properties of the LC materials render them to become promising candidates for OLED applications. Their electroluminescence competence was studied by fabricating doped and non-doped simple-architecture OLED devices. One of the doped devices with Py-2 as the emissive layer exhibits the highest deep-green electroluminescence with a brightness of 1898 cd m−2 at 4.23 V having CIE coordinates of (0.312, 0.606).
Certainly, the emissive layer is a vital component that determines the overall efficiency of the device. Till today, a large variety of luminescent materials have been developed in order to improve the device performance.9–17 Presently, one of the major challenges is the development of efficient fluorophores with high charge transport characteristics in addition to preserving the solid-state emission for high-performance non-doped OLEDs. In this context, columnar liquid crystals (CLCs) have proven to be better alternatives to the insulating amorphous solids and expensive single-crystal fluorophores due to their effective combination of π–π self-stacking with long-range order, self-healing ability, easy processability, good luminescence ability, and intrinsic charge carrier property in the soft condensed state.18–24
In the columnar phase, molecular discs stack on the top of the other to form columns that self-organize into different lattices. Here, the intracolumnar (core–core) separation of the aromatic discs is usually of the order of 0.35 nm; therefore, there is considerable overlap between the π orbitals. On the other hand, the intercolumnar (column–column) separation is commonly 2–4 nm, depending on the length of the peripheral aliphatic chains. Therefore, intracolumnar interactions between neighboring molecules within the columns are much stronger than intercolumnar interactions. The columnar phase provides a facile path for the movement of charges via a hopping process. In CLCs, conductivity along the columns has been observed to be several orders of magnitude higher than that in the perpendicular direction. Time-of-flight charge mobility up to about 0.1 cm2 V−1 s−1 has been realized in columnar mesophases. As the mobility of the charge carriers is a key factor in determining the device performance (e.g., OLEDs, solar cells, sensors, etc.), these materials have promising applications in such optoelectronic devices.25,26 Therefore, the use of luminescent CLCs as the emissive layer in OLEDs can enhance the device performance due to their high charge carrier mobility caused by the long-range order along with their intense luminescence properties. Hence, CLC-based OLEDs can be used as a potential backlight for liquid crystal displays (LCDs) by replacing the expensive backlight and absorbing color filters, which correspondingly reduces the overall cost of the device and significantly enhances the emission efficiency.27–29 In this context, considerable efforts have been focused on developing luminescent liquid crystals with decent charge mobility and employing them as active components in fabricating electroluminescent devices.
Recently, few OLEDs comprising columnar fluorescent materials as the sole emissive layer and/or as an emissive dopant ensued with noticeable external quantum efficiency have been reported.27,30–33 In CLCs, notorious aggregation-caused quenching effect is a common occurrence, mainly due to the principal intermolecular interactions at the ordered arrangements of the molecules. In order to maintain the significant exciton emission in the mesophase, various molecular designs have been explored.34,35 Among the most successful designs, employing the donor–acceptor (D–A) moieties in the core structure was found to be an excellent approach; therefore, easy tailoring of essential optical and electrochemical properties is possible. Moreover, the proper selection of donor and acceptor scaffolds is important in order to ensure their efficient D–A interactions, subsequently influencing the intramolecular charge transfer (ICT) property, and hence, tuning the HOMO–LUMO energy bandgap.
On the basis of our continuous effort in this context,36–40 we have rationally designed a new class of nonsymmetrical D–A–D-structured mesogens, Py-1 to Py-3, for OLED applications. In the new design, π-rich 9,10-didodecyloxyphenanthrene and trialkoxybenzene units have been selected as effective electron donors, while 3-cyanopyridone moiety as an efficient electron acceptor to achieve optimum optoelectronic properties at the liquid crystalline state (Fig. 1). It is expected that mesogens containing a phenanthrene core, because of its polycyclic aromatic hydrocarbon (PAH) structure, may possess good self-assembling property with effective π-orbital overlapping, which, in turn, reduces the intercolumnar spacings yielding good charge migration ability through the columnar stack. Moreover, the introduction of additional alkoxy donors in electron-rich phenanthrene attached to electron-deficient cyanopyridone offers efficient D–A interactions. Consequently, the designed mesogens would exhibit necessary optoelectronic properties for their use in OLED devices. In the present work, all the final compounds (Py-1 to Py-3) were synthesized through simple and efficient synthesis protocols. They were effectively characterized using different spectral techniques. Their mesomorphic, photophysical, electrochemical, and theoretical studies were comprehensively undertaken. Finally, we investigated their electroluminescence ability as emitting materials by fabricating multilayer OLED device structures.
Compound | Phase sequence | |
---|---|---|
Heating | Cooling | |
a Peak temperatures, °C (enthalpy/kJ mol−1) obtained by second heating and first cooling at the rate of 5 °C min−1; Colr = columnar rectangular phase; Colh = columnar hexagonal phase; I = isotropic liquid phase. | ||
Py-1 | Colr 89.48 (1.09) Colh 104.30 (0.20) I | I 96.1 (−0.50) Colh 75.52 (−1.12) Colr |
Py-2 | Colr 112.20 (2.36) Colh 132.95 (2.04) I | I 130.80 (−1.21) Colh 101.0 (−2.37) Colr |
Py-3 | Colr 73.69 (0.24) Colh 121.19 (1.41) I | I 116.20 (−1.08) Colh 55.10 (−0.19) Colr |
The DSC thermograms of Py-1 to Py-3 are shown in Fig. 2a–c. Apparently, the DSC trace of compound Py-1 did not show any signs of melting on the heating scan; instead, it displayed two distinct transitions at 89.48 °C and 104.30 °C with smaller enthalpy changes of 1.09 kJ mol−1 and 0.20 kJ mol−1 due to LC–LC and LC–I transitions, respectively (Fig. 2a). In the cooling cycle, both the transition peaks reoccurred at 96.10 °C and 75.52 °C without any crystallization transitions till reaching room temperature. The perceived very low enthalpy changes may be attributed to the highly fluidic nature of the mesophases. Compound Py-2 carrying longer alkyl chains also showed two separate mesophases at a relatively higher temperature, having a clearing point at 132.95 °C than that of Py-1. On cooling, both the LC phases reappeared and did not exhibit any signals of crystallization, as shown in Fig. 2b. Further, analog compound Py-3 bearing much longer terminals (hexadecyloxy) displayed two clear mesomorphic states at 121.19 °C (Fig. 2c). It was observed that this set of compounds has not shown any regular trend in their mesophase thermal stability despite the fact that there exists a linear increase in the alkyl chain length in the phenyl arm.
Fig. 2 DSC thermograms: (a) Py-1; (b) Py-2; (c) Py-3 (red and blue traces represent second heating and first cooling cycles, respectively). |
Under POM, a highly birefringent mosaic pattern was observed upon the slow cooling of compound Py-1 from its isotropic state, which was high fluidic and shearable even at room temperature (Fig. 3a and b). This is a typical indication of the existence of columnar mesomorphism.25 Moreover, upon cooling down from the higher temperature mesophase to its lower one, a remarkable decline in the optical birefringence was noticed in some of the bright areas, as shown in Fig. 3a and b, which may be due to the inter and/or intracolumnar transitions. The observed optical textural changes were fairly consistent with the DSC transitions. However, in the case of Py-2, dendritic growth appeared initially, which, in turn, formed a typical mosaic pattern at the lower temperature LC phase and it remained unchanged until the temperature was reduced to much lower values (Fig. 3c and d). As seen in Fig. 3d and e, compound Py-3 displayed similar characteristic optical textures for columnar phases featuring a combination of mosaics with linear and fan-shaped birefringent defects as well as homeotropic regions. The POM images of Py-1 to Py-3 captured in both the mesophase ranges are shown in Fig. 3a–f.
In order to obtain further insights into the self-organization of the molecules in the different mesophase structures, powder XRD studies were carried out for non-aligned samples of all the new mesogens. As indicated by the DSC traces, they were found to be bi-mesomorphic in nature. Definitely, the XRD patterns gained for Py-1 in both the LC phase ranges were fairly different; indeed, they are almost similar within their respective mesophase range at different temperature points (Fig. 4a and b). For instance, the XRD trace at 90 °C (within the higher temperature mesophase range) showed two sharp reflections in the lower angle region in the reciprocal ratio of 1:√3. However, in the wide angle region, a rather diffused halo was observed at 4.39 Å, similar to the liquid-like aliphatic chains (Fig. 4a). The observed two lower angle signals can be assigned to the (10) and (11) planes with hexagonal symmetry for a = 30.41 Å. In fact, only these reflections do not unambiguously confirm the formation of a hexagonal lattice. Nevertheless, such observations are frequent in hexagonal mesophases bred by diverse mesogenic structures.42–49 This may be due to the minimum in the form factor, which prevents the appearance of peaks in the lower angle region. Moreover, the appearance of typical optical textures confirm the presence of a columnar hexagonal phase. The lattice area S and molecular volume V were estimated to be 801 Å2 and 3517 Å3, respectively.
Fig. 4 XRD patterns obtained for Py-1 at various temperatures in the (a) higher and (b) lower temperature mesophase ranges. |
The XRD pattern of the lower temperature mesophase range (obtained at room temperature) showed a number of reflections in the lower angle region (Fig. 4b). In addition, a broad halo centered at 4.43 Å due to alkyl chain correlations was observed. The set of signals are assigned to the (01), (11), (21), (30), (31), and (32) diffractions of the rectangular lattice with the unit cell parameters a = 33.86 Å and b = 26.01 Å.
Similarly, the XRD patterns were obtained at discrete temperatures in both the mesophase ranges of Py-2, as shown in Fig. S22 (ESI†). Evidently, the patterns obtained at 128 °C and 115 °C reveal that the reciprocal d-spacings of the lower angle reflections are in the ratio of 1:√3 and they can be attributed to the (10) and (11) planes of the hexagonal lattice. Their lattice parameters were calculated to be 32.34 and 32.36 Å, respectively. However, the XRD pattern at the lower temperature mesophase of Py-2 (obtained at 25 °C) revealed a set of reflections that can be certainly assigned to the columnar rectangular phase because a = 33.79 Å and b = 27.72 Å (Fig. S22, ESI†). Similarly, mesogen Py-3 adopted the Colr and Colh phases at lower and higher temperatures, respectively, as shown in Fig. S23 (ESI†). A detailed XRD index is summarized in Table 2. From these results, it is evident that no generic trend was noticed in the thermal stability of mesophases in spite of the systematic sequential variations in the lengths of the peripheral chains. Therefore, mesophase types and ranges are independent of the terminal chain lengths in these molecules. This may be due to numerous structural conformations of the two arms with lengthy flexible chains of the central cyanopyridone core. However, all the compounds have organized into similar mesophases with two different lattice structures.
Compd | Phase (T/°C) | d obs [Å] | d cal [Å] | Miller indices (hk) | Lattice parameter a [Å], lattice area S [Å2], cell volume V [Å3] |
---|---|---|---|---|---|
d obs, observed spacings; dcal, calculated spacings; ha, alkyl chains correlation peak value; hc, π–π spacing; Z, number of molecules per columnar slice. Alkyl halo was considered for the calculations when the core–core peak is absent. | |||||
Py-1 | Colh (90) | 26.34 | 26.03 | (10) | a = 30.41 |
15.15 | 15.20 | (11) | S = 801.1 | ||
4.39 (ha) | V = 3516.9 | ||||
Z = 1.88 | |||||
Colr (25) | 26.01 | 26.01 | (10) | a = 33.86 | |
20.60 | 20.59 | (11) | b = 26.01 | ||
13.80 | 14.18 | (21) | S = 880.7 | ||
11.13 | 11.28 | (30) | V = 3901 | ||
10.22 | 10.35 | (31) | Z = 2.08 | ||
8.45 | 8.50 | (32) | |||
4.43 (ha) | |||||
Py-2 | Colh (115) | 28.03 | 28.03 | (10) | a = 32.36 |
16.13 | 16.18 | (11) | S = 907.2 | ||
4.48 (ha) | V = 4064 | ||||
Z = 1.89 | |||||
Colr (25) | 27.72 | 27.72 | (01) | a = 33.79 | |
21.43 | 21.43 | (11) | b = 27.72 | ||
15.99 | 16.89 | (20) | S = 936 | ||
14.51 | 14.43 | (21) | V = 3587 | ||
12.79 | 12.82 | (12) | Z = 1.66 | ||
8.88 | 8.91 | (13) | |||
3.83 (hc) | |||||
4.40 (ha) | |||||
Py-3 | Colh (80) | 30.05 | 30.05 | (10) | a = 34.69 |
17.29 | 17.34 | (11) | S = 1042 | ||
4.45 (ha) | V = 4645.5 | ||||
Z = 1.91 | |||||
Colr (25) | 29.66 | 29.66 | (01) | a = 34.06 | |
22.37 | 22.36 | (11) | b = 29.66 | ||
17.13 | 17.03 | (20) | S = 1010 | ||
15.25 | 14.83 | (02) | V = 4424 | ||
13.58 | 13.59 | (12) | Z = 1.82 |
The obtained results indicated that all the members of the series displayed two distinct columnar mesophases as a function temperature. Compound Py-2, with the critical chain length among the series, was selected to be the representative example to understand the molecular assembly in the mesomorphic states. Initially, the number of molecules occupied in each columnar stratum (Z) was estimated by assuming the density equal to 1 g cm−3.50 Accordingly, nearly two molecules are involved in each columnar slice of both the mesophases to ensure that the space is filled by the disc-like structure. It should be noted that the central cyanopyridone core, capable of forming closed-type H-bonding, may stabilize the dimeric unit through strong intermolecular H-bonding.
As evident from many classical and unconventional discotic materials, all the compounds showed a thermodynamic intercolumnar transition from rectangular to hexagonal columnar assemblies, which was exhibited by the observed small enthalpy changes, optical variations, and differences in XRD patterns.51 Further, the dimeric structures form a columnar array with rectangular and hexagonal symmetries, wherein the position of the molecules is not fixed; in fact, it is truly liquid-like. This may be attributed to its propeller-like structures whose conformational motions increase the mesogenic fluctuations and intracolumnar tilting, which could be responsible for the disappearance of the core–core peak in the XRD pattern for Colh. This type of mesophase is sometimes termed as “disordered columnar mesophases” in order to distinguish from the ordered assemblies.52 However, these molecules may possess some degree of order due to the intermolecular H-bonding along the columnar axis through the central ring. In addition, its D–A–D core structure would also stabilize the mesophase by strong intracolumnar D–A interactions. Considering these facts, we proposed a schematic model for the molecular self-assembly of Py-2 in Colr and Colh with plausible H-bonding interactions (Fig. 5).
Compd | λ abs (nm) | λ em (nm) | Stokes shift (cm−1) | E gopt (eV) | λ em (nm) | Φ F | τ (ns) τ1/τ2 |
---|---|---|---|---|---|---|---|
a Estimated for thin films. b Absolute quantum yield determined using an integrated sphere. c Fluorescence lifetime at the excitation wavelength, λexc = 350 nm. | |||||||
Py1 | 259, 302, 394 | 501 | 5420 | 2.72 | 504 | 0.52 | 2.39/4.31 |
Py2 | 258, 300, 395 | 502 | 5396 | 2.73 | 506 | 0.49 | 2.41/4.61 |
Py3 | 258, 300, 395 | 502 | 5396 | 2.75 | 508 | 0.48 | 2.28/3.71 |
The fluorescence lifetime of new mesogenic materials was estimated for the DCM solution samples (c = 2 × 10−5 M) using the TCSPC technique by probing at their respective emission maxima. The resultant fluorescence kinetic decay profiles are shown in Fig. 8a. The traces fitted with the biexponential decay showed average lifetime values of 2.54 (χ2 = 1.0), 2.51 (χ2 = 0.99), and 2.51 (χ2 = 1.01) for Py-1, Py-2, and Py-3, respectively (Table 3). The same samples were illuminated under a longer wavelength and their photographs are shown in Fig. 6b. To investigate the PL behavior of these materials at the liquid crystalline state, their neat thin films were prepared by the spin coating technique and the fluorescence spectra were obtained by exciting them at their respective solution absorption maxima (Fig. 6c). Interestingly, the emission wavelength (504–508 nm) exhibited marginal shifts when compared to the solution emission maxima (501–502 nm). A visually perceivable emission was observed under light illumination of 365 nm, as shown in Fig. 6d.
Fig. 6 (a) Fluorescence decay profiles obtained for DCM solution and (b) their emission hue; (c) fluorescence spectra obtained for thin films and (d) their emission hue. |
Further, the effect of solvent on the optophysical properties of these emitting LC materials was examined by studying the absorption and emission characteristics of a representative compound, namely, Py-1. Its UV-visible and fluorescence spectra are shown in Fig. S25 (ESI†), and the relevant data are compiled in Table S1 (ESI†). Evidently, the absorption profile showed a lack of solvent dependence, indicating a nonpolar ground state. However, a slight red-shift in the emission bands on the increasing solvent polarity demonstrated the trivial positive fluorescence solvatochromism. Notably, the unusual bathochromic shift perceived in the DCM arises due to the effective solvation in the solvent induced by the instant stabilization of polarizable electrons during electronic excitation.53
Conclusively, the observed larger Stokes shift, biexponential PL decay, and nonlinear solvatochromic shift indicated the existence of locally excited (LE), as well as charge transfer (CT), states in these D–A–D luminogens. In addition, density functional theory (DFT) calculations reveal a slight twist in the donor moieties with respect to the central acceptor core, suggesting that the second exciton species might have arisen due to the twisted intramolecular charge transfer (TICT).54 This type of coexistence of LE and CT characteristics is generally called the “hybridized local and charge transfer” (HLCT) state, which is known to contribute toward the enhancement of fluorescence radiative decay, which improves the electroluminescence efficiency of OLEDs.55–57
Compd | E 1red (V) | E 1oxd (V) | E LUMO (eV) | E HOMO (eV) | E gCV (eV) | E gopt (eV) |
---|---|---|---|---|---|---|
a Onset potential of the first reduction wave. b Onset potential of the first oxidation wave. c E LUMO = −[4.8 − E1/2,Fc/Fc+ + E1red] eV. d E HOMO = −[4.8 − E1/2,Fc/Fc+ + E1oxd] eV, where E1/2,Fc/Fc+ was found to be 0.51 V. e E gCV = ELUMO − EHOMO. f Optical bandgap. | ||||||
Py1 | −0.83 | 1.45 | −3.46 | −5.74 | 2.28 | 2.72 |
Py2 | −0.87 | 1.44 | −3.41 | −5.73 | 2.32 | 2.73 |
Py3 | −0.86 | 1.41 | −3.43 | −5.70 | 2.27 | 2.75 |
To study the FMO distributions in these new molecules, DFT calculations were performed using GAUSSIAN-09 program with the Becke's three-parameter functional and Lee, Yang, and Parr correlation (DFT-B3LYP). In the simulation study, the longer alkoxy chains are replaced by methoxy groups in the model molecular structure to reduce computational time and cost. We presumed that reducing the length of the alkyl chains would not affect the required energy parameters. Its geometrically optimized structure was obtained by using the basic set 6-311G(d,p) (Fig. S24, ESI†). The corresponding simulated energy-minimized structure and HOMO–LUMO levels are shown in Fig. 7. Apparently, both dialkoxyphenanthrene and trialkoxyphenyl rings are not coplanar with the central cyanopyridone core, which resulted in a bowl-shaped structure. As shown in Fig. 7, the HOMOs are concentrated over the dialkoxyphenanthrene and cyanopyridone rings, while LUMOs are delocalized throughout the molecule. These results confirm the presence of a moderate ICT behavior, which validates the experimental electro-optical studies.
Device I: ITO/PEDOT:PSS/Py-2/LiF/Al.
Device II: ITO/PEDOT:PSS/PVK:Py-2/LiF/Al.
Device III: ITO/PEDOT:PSS/PVK:Py-2/BCP/Alq3/LiF/Al.
In case of device I, Py-2 acted as the sole emissive material; however, in devices II and III, 10 wt% of Py-2 doped in the host poly(9-vinylcarbazole) (PVK) served as the emissive material. In the device fabrication, we used patterned indium tin oxide (ITO)-coated glass substrate as a transparent anode. Moreover, poly(3,4-ethylenedioxy-thiophene)/poly(styrene-sulfonate) (PEDOT:PSS) was used as the hole-injection material, which can also facilitate the smoothening of the ITO surface, thereby reducing the turn-on voltage and probability of electric shorts. This, in turn, extends the lifetime of the device.58,59 PVK possesses the ability to form excellent films and it also has good miscibility with numerous emitting materials. Hence, it was selected as the host material in device configurations II and III. Bathocuproine (BCP) served as the hole-blocking material (HBM) to restrict the holes from moving toward the emitting layer, whereas tris-(8-hydroxyquinoline)aluminum (Alq3) functioned as the electron-transport material (ETM) to assist electron injection into the emitting layer. For facilitating electron injection, a bilayer cathode comprising lithium fluoride (LiF) and aluminum (Al) was used in the device structures; here, LiF acts as the electron injection material. Table 5 summarizes the key performance data of the newly fabricated LC-based OLEDs.
Device | V onset (V) | L max (cd m−2) | η c (cd A−1) | η p (lm W−1) | η EQE (%) |
---|---|---|---|---|---|
a V onset, turn-on voltage at luminance of 1 cd m−2. b Luminance at 20 V. c Current efficiency. d Power efficiency. e External quantum efficiency at 100 cd m−2. | |||||
I | 7.07 | 258 | 0.44 | 0.12 | 0.29 |
II | 5.79 | 1463 | 1.33 | 0.38 | 0.73 |
III | 4.23 | 1898 | 1.65 | 0.66 | 0.98 |
Fig. 8c shows the J–V–L features of the fabricated OLEDs. Device I comprising only Py-2 as the emissive material showed low luminance (Lmax) of 258 cd m−2 with current efficiency (ηc) of 0.44 cd A−1, power efficiency (ηp) of 0.12 lm W−1, and external quantum efficiency (ηEQE) of 0.29% at 100 cd m−2. Further, the high drive voltage (Vonset, 1 cd m−2) of the device was found to be as high as 7.07 V. However, drastic enhancement in the device performance was observed in which PVK:Py-2 (10 wt%) was used as the emitting composite (device II). The increase in the performance of device II can be ascribed to the fact that there is an effective transfer of the exciton energy from PVK (host material) to Py-2 (emissive dopant).58,59 Although device II showed superior performance as compared to device I, it still exhibited a high Vonset value (5.79 V), indicating the presence of high charge injection barriers in the device. A balanced flow of charge carriers (electrons and holes) is important to obtain maximum recombination, which eventually will result in improved performance of the devices as the imbalanced charge transport in the emissive layer hampers the performance of the device. Hence, to further improve the device performance and reduce the drive voltage, BCP and Alq3 were used as HBM and ETM, respectively which is designated as device III. Consequently, device III showed an improvement in the device performance (Lmax of 1898 cd m−2, ηc of 1.65 cd A−1, ηp of 0.66 lm W−1, and ηEQE of 0.98%) with a significant reduction in Vonset (4.23 V) as compared to device II. The improved device performance can be attributed to the effective transfer of exciton energy from PVK (host) to Py-2 (dopant) as well as the balanced charge transport in the emissive layer.60–62 Further, the use of BCP as HBM assisted in confining the reductant holes in the emitting layer, which did not recombine with the electrons in the emitting zone.62–65
All the fabricated OLEDs emitted green light when ITO was positively biased. Fig. 8d shows the EL spectra of the devices at 20 V with the peak at ∼531 nm and FWHM of ∼72 nm. From Fig. 8d (inset), it is evident that the thin-film PL spectra of PVK and PVK:10 wt% Py-2 exactly overlap with each other, revealing that both originate from the same excited state. In addition, the shapes of the EL spectra of the devices were similar to the thin-film PL spectra of PVK:Py-2 (Fig. 8d), which is also due to the same excited state origin. The devices demonstrated excellent spectral stability as the EL spectra, over a wide range of operating voltages, did not show any changes in the shapes and peaks. This also indicates that during device operation, Py-2 exhibits excellent thermal stability. The CIE chromaticity coordinates determined using the EL spectra of the OLEDs at 20 V are (0.312, 0.606) corresponding to green emission. It is noteworthy that the investigated OLEDs are unoptimized. Further optimizations can improve the device performance. The results reveal that these phenanthrene–cyanopyridone-based emissive LC materials have promising potential in OLED applications with further scope for improvement in molecular design and device architecture.
Footnotes |
† Electronic supplementary information (ESI) available. See DOI: 10.1039/c8qm00377g |
‡ H. Ulla designed, executed and analyzed the OLED investigations. |
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