δ-Carboline-based bipolar host materials for deep blue thermally activated delayed fluorescence OLEDs with high efficiency and low roll-off characteristic

Abstract

Two bipolar host materials, 8-(9H-carbazol-9-yl)-5-(pyridin-2-yl)-5H-pyrido[3,2-b]indole (CzCbPy) and 5-(6-(9H-carbazol-9-yl)pyridin-2-yl)-8-(9H-carbazol-9-yl)-5H-pyrido[3,2-b]indole (2CzCbPy), were synthesized for deep blue thermally activated delayed fluorescence organic light emitting diodes (TADF OLEDs). Both CzCbPy and 2CzCbPy hosts possess bipolar characteristic with high polarity, which results in high delayed photoluminescence quantum yields by reducing the energy gap between singlet and triplet states of TADF materials. In addition, these hosts have high enough triplet energies of 3.05 eV to transfer exciton energy to a deep blue TADF emitter. A deep blue TADF OLED fabricated with a CzCbPy host exhibited high external quantum efficiency of 22.9% and low efficiency roll-off (19.2% at 1000 cd m⁻²).

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Introduction

Thermally activated delayed fluorescence (TADF) OLEDs have recently attracted great attention because they can achieve a theoretical maximum internal quantum efficiency (IQE) of 100% by harvesting both singlet and triplet excitons for light emission.^1–6 In TADF OLEDs, triplet excitons are readily up-converted into the singlet state by reverse intersystem crossing (RISC) owing to extremely small singlet-triplet energy differences, then all singlet excitons can emit either prompt fluorescence or delayed fluorescence.^7,8 To date, a lot of TADF materials with external quantum efficiencies (EQEs) of over 20% have been reported.^9–11 However, many TADF OLEDs, specially blue TADF OLEDs, have a problem of high efficiency roll-off due to the exciton-polaron quenching and triplet-triplet annihilation (TTA). To avoid this problem and achieve high efficiency, TADF materials are usually dispersed in a suitable host matrix at a relatively low concentration. Hence, an ideal host should possess high triplet energy (T₁), appropriate frontier molecular orbital levels, bipolar charge transport ability, and large spectral overlap with doped emitters.

To date, many studies on deep blue TADF OLEDs have been carried out by using unipolar hosts such as 3,3′-bis(8a,9a-dihydro-9H-carbazol-9-yl)-1,1′-biphenyl (mCBP) and 1,3-di(9H-carbazol-9-yl)benzene (mCP) are the representative example of hole type hosts.^12–14 Bis[2-(diphenylphosphino)phenyl] ether oxide (DPEPO) and (2,8-bis(diphenylphosphine oxide)-dibenzofuran) (DBFPO) are the most common electron type hosts.^12,15,16 These phosphine oxide-based hosts have been applied to various deep blue TADF dopant to achieve high efficiency. However, they induce a narrow emission zone due to their unbalanced charge transportation, resulting in high probability of TTA process. In addition, the bonding dissociation energy of their phosphorus–carbon bond is very low. Therefore, the use of phosphine oxide based materials cannot avoid the disadvantages of high driving voltage, serious roll-off phenomena, and short device lifetime.¹⁷ In order to overcome these issues, several high T₁ bipolar hosts without phosphine oxide unit have been developed. Most high T₁ bipolar hosts was mainly based on carbazole as hole transport unit and benzimidazole,¹⁸ cyano,¹⁹ and benzimidazobenzothiazole²⁰ as electron transport unit. For the first example, Dongge Ma and co-workers reported three bipolar host materials connecting carbazole-based mCP to benzimidazole units by changing the position of a benzimidazole.¹⁸ The ortho-linked molecule exhibited the highest T₁ (3.0 eV). In other case, Lian Duan and co-workers synthesized the four host materials, carbazole connecting with cyano units possessed the high T₁ levels (2.87–3.03 eV).¹⁹ And finally, Adachi group reported two bipolar hosts connecting benzimidazobenzothiazole and carbazole, and they showed T₁ value of 3.02–3.04 eV.²⁰ Even though these materials have been reported, it is necessary to develop new high T₁ bipolar host for the much better deep blue TADF OLEDs.

In this study, we synthesized 8-(9H-carbazol-9-yl)-5-(pyridin-2-yl)-5H-pyrido[3,2-b]indole (CzCbPy) and 5-(6-(9H-carbazol-9-yl)pyridin-2-yl)-8-(9H-carbazol-9-yl)-5H-pyrido[3,2-b]indole (2CzCbPy) as the high triplet energy bipolar host materials based on carboline and pyridine as electron transport unit and carbazole as hole transport unit. Both CzCbPy and 2CzCbPy hosts showed high T₁ of about 3.0 eV and high maximum EQE of 22.9% and low efficiency roll-off characteristic (19.2% at 1000 cd m⁻²) in TADF blue OLEDs fabricated with bis[4-(9,9-dimethyl-9,10-dihydroacridine)phenyl]sulfone (DMAC-DPS)⁸ as TADF blue dopant. This is the first example of bipolar host without phosphine oxide unit reporting high maximum EQE of above 20% in DMAC-DPS based OLED.

Results and discussion

Material design and synthesis

Two host materials were designed to possess high triplet energy and bipolar charge transport properties by coupling carbazole as an electron-rich moiety and pyridine as an electron-deficient moiety and δ-carboline as a bipolar moiety. δ-Carboline has high triplet energy than carbazole and bipolar property due to its electron-deficient pyridine unit in the structure. Therefore, carbolines with pyridine unit have been used as an electron transport unit of some high triplet energy host materials.^21–23 Since carbazole unit is a strong donor and pyridine unit is a weak acceptor, δ-carboline with weak acceptor property was incorporated into the hosts to improve the balance of hole and electron transport property. To keep the high triplet energy of the carbazole and δ-carboline units, all moieties were connected each other through C–N bonds because such substitution limits the extension of conjugation. Therefore, it was expected that all hosts could show high triplet energy and bipolar charge transport properties. Two host materials, CzCbPy and 2CzCbPy, were prepared by two copper-catalyzed Ullmann couplings of halogenated compounds with amines (Scheme 1) and purified successively by column chromatography and vacuum train sublimation yielding highly pure compounds with a purity above 99%. The chemical structures were characterized by ¹H and ¹³C NMR and high resolution mass spectrometer (HRMS).

Scheme 1 Synthesis of CzCbPy and 2CzCbPy.

Theoretical calculations

A molecular simulation was carried out to understand the physical properties of CzCbPy and 2CzCbPy at the molecular level (Table 1). Theoretical calculations were performed using density functional theory (DFT) calculation with B3LYP in Dmol3. The optimized structures and the HOMO and LUMO orbitals for CzCbPy and 2CzCbPy are shown in Fig. 1. The HOMOs of both hosts are mainly distributed over the carbazole near the δ-carboline side and partly the δ-carboline. Therefore, the HOMO levels of these hosts are same as −5.0 eV. On the other hand, the LUMO orbitals of these hosts are differently dispersed: the LUMO of CzCbPy is only observed in the δ-carboline, while the LUMO of 2CzCbPy is localized not only on the δ-carboline but also on the pyridine. As a result, the LUMO levels of two hosts are different from each other.

Table 1 DFT calculation results in energy levels, torsion angles and dipole moment of CzCbPy and 2CzCbPy

Host	HOMO (eV)	LUMO (eV)	Eg (eV)	T1 (eV)	θ1 (°)	θ2 (°)	Dipole moment (μ)
CzCbPy	−5.00	−1.00	4.00	3.07	50.7	—	4.64
2CzCbPy	−5.00	−1.14	3.86	3.02	50.9	39.9	4.60

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Fig. 1 Molecular structures and HOMO/LUMO distributions of CzCbPy and 2CzCbPy in geometry optimization state by DFT simulation with B3LYP/6-31G*.

The LUMO level of 2CzCbPy is −1.4 eV, which is 0.14 eV lower than that of CzCbPy, implying that the additional carbazole in 2CzCbPy reduced the LUMO level of 2CzCbPy. The HOMOs of both host materials were formed at carbazole moiety and the LUMOs were formed at carboline and pyridine moieties. Since the HOMO is in hole transport type moiety and LUMO is in electron transport type moieties, bipolar transport property of our two hosts was expected. In addition, these hosts also show well separated HOMO and LUMO orbitals, which could result in bipolar characteristic. The calculated triplet energy levels of CzCbPy and 2CzCbPy were 3.07 eV and 3.02 eV, respectively. The T₁ of CzCbPy is slightly higher than that of 2CzCbPy. To understand the reason of this difference, we investigated the torsion angle between carbazole, δ-carboline, and pyridine. The angles (θ₁) between carbazole and carboline for CzCbPy and 2CzCbPy were similar and they were 50.5° and 50.9°, respectively, which are large enough to make two moieties well separated. However, 2CzCbPy has additional carbazole and the angle (θ₂) between carbazole and pyridine is 39.9°, which is small and makes the conjugation length longer, resulting in lower T₁. In addition, the molecular dipole moments of two hosts were calculated at ground states. The dipole moment of CzCbPy is 4.64 μ, which is slightly higher than that of 2CzCbPy (4.60 μ), due to the greater asymmetry of CzCbPy. From the molecular dipole moment, we speculated that CzCbPy would make slightly higher polar environment than 2CzCbPy.

Table 2 The photo-physical and electro-physical properties of CzCbPy and 2CzCbPy

Host	λabs^a (nm)	λRTPL^a (nm)	Eg^c (eV)	HOMO^d (eV)	LUMO^e (eV)	T1^b (eV)
a Measured in toluene solution of 10^−5 M at room temperature.b Measured in toluene solution of 10^−5 M at 77 K. The triplet level was estimated from the first peakt of the phosphorescence spectra.c The optical band gap energy was determined from edge of the absorption spectrum.d HOMO levels were obtained using cyclic voltammetry.e LUMO levels were calculated from optical band gap and HOMO.
CzCbPy	286, 338	355	3.50	6.12	2.62	2.98
2CzCbPy	293, 337	399	3.38	6.06	2.68	2.97

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Material properties

The thermal properties of CzCbPy and 2CzCbPy were examined by differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA) and their thermograms are shown in Fig. S1† and summarized in Table S1.† The glass transition temperature (T_g) of 2CzCbPy (138 °C) is higher than that of CzCbPy (81 °C). These values are higher than that of the well-known blue host material, 1,3-bis(N-carbazolyl)benzene (mCP)²⁴ (60 °C). The decomposition temperatures (T_d) of CzCbPy and 2CzCbPy were 321 °C and 412 °C, respectively. Overall, 2CzCbPy showed much higher thermal stability than CzCbPy, due to the higher molecular weight by additional carbazole moiety. Photophysical properties of CzCbPy and 2CzCbPy were examined using UV-vis and photoluminescence (PL) spectroscopies. Fig. 2 shows UV-vis absorption and PL spectra of CzCbPy and 2CzCbPy. The CzCbPy exhibited absorption peaks at 286, 338 nm, and 2CzCbPy indicated at 293, 337 nm, respectively. Both peaks of 338 and 337 nm are assigned to the π–π* transition of CzCbPy and 2CzCbPy, respectively. The band gap energy (E_g) of CzCbPy and 2CzCbPy calculated from the absorption edge of UV-vis spectra are 3.50 eV and 3.38 eV, respectively. The band gap of CzCbPy is 0.12 eV wider than 2CzCbPy, which is similar to the simulation results. The phosphorescence spectra of CzCbPy and 2CzCbPy revealed their T₁ as ~3.0 eV for both TADF hosts. Thus, T₁ of both hosts are higher than that of common carbazole-based host, mCP (2.9 eV)²⁵ and high enough for application in deep blue TADF OLEDs. The HOMO levels of CzCbPy and 2CzCbPy measured by cyclic voltammetry (Fig. S2†) are −6.12 eV and −6.06 eV, respectively. LUMO levels of CzCbPy (−2.62 eV) and 2CzCbPy (−2.68 eV) are estimated from E_g and HOMO levels. Measured HOMO and LUMO values of both hosts have similar tendency with molecular simulation data even though absolute values are different due to approximate quantum mechanics calculation. The HOMO levels of these two hosts are similar to that of mCP (−5.9 eV), whereas the LUMO levels are much deeper than that of mCP (−2.4 eV), due to the additional electron acceptor moieties (Table 2).

Fig. 2 UV-vis absorption (black dash line), PL spectrum at 300 K (black solid line) and 77 K (red solid line) in toluene 10⁻⁵ M solution. (a) CzCbPy, (b) 2CzCbPy.

Table 3 Exciton lifetime and the rate constant comparison between mCP and new host materials

Host	τP^a (ns)	τD^b (μs)	ΦPL^c (%)	ΦP^d (%)	ΦD^e (%)	kP (10^7 s^−1)	kD (10^5 s^−1)	k^Sr (10^6 s^−1)	kISC (10^7 s^−1)	kRISC^f (10^6 s^−1)	k^Tnr^g (10^4 s^−1)
a Exciton lifetime of prompt components of 20% doped film with DMAC-DPS.b Exciton lifetime of delayed components of 20% doped film with DMAC-DPS.c PLQY measured with integral sphere.d Divided prompt component from PLQY.e Divided delayed component from PLQY.f Rate constant of reverse intersystem crossing from T1 to S1.g Rate constant of non-radiative decay from T1 to ground state (S0).
mCP	23.88	4.03	0.67	0.17	0.50	4.17	2.48	7.08	3.46	0.879	9.87
CzCbPy	18.83	3.10	0.76	0.16	0.60	5.31	3.23	8.50	4.46	1.44	9.22
2CzCbPy	20.59	3.29	0.72	0.16	0.56	4.86	3.04	7.77	4.08	1.27	10.10

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Photophysical properties

To investigate the applicability of two hosts in TADF OLED, 20% doped films of DMAC-DPS in the hosts and mCP were prepared. The prompt and delayed PL spectra were similar for all hosts (Fig. S3†). This indicates that the spectra originated from only DMAC-DPS and the energy of these hosts is well transferred to the dopant. The prompt PL spectrum in mCP film was 466 nm, and those in CzCbPy and 2CzCbPy were 474 nm. Since CzCbPy and 2CzCbPy have higher dipole moment and create more polar condition for DMAC-DPS than mCP, the CT state (S₁) of DMAC-DPS was more stabilized in CzCbPy and 2CzCbPy, resulting in the red-shift of the spectra. This result implies that the emission characteristics of the dopant may be varied with the host. As shown in Fig. 3, the transient PL decay curve of the films measured under nitrogen atmosphere clearly exhibits both a nanosecond-scale prompt component and a micro-second-scale delayed component at room temperature (300 K). The prompt lifetimes were similar in all three hosts, about 20 ns, but the delayed exciton lifetime was shorter in CzCbPy and 2CzCbPy (3.10 and 3.29 μs, respectively) than in mCP (4.03 μs). As mentioned above, S₁ of the dopant is more stabilized in polar CzCbPy and 2CzCbPy, which leads to the decrease of ΔE_ST and short delayed exciton lifetime. The overall PL quantum yields (PLQYs) were 67.32, 75.90, and 72.19% for mCP, CzCbPy, and 2CzCbPy, respectively (Table 3). The prompt components of PLQYs in mCP, CzCbPy, and 2CzCbPy were similar, 17.17, 15.86, and 15.59%, and the delayed ones were different, 50.15%, 60.04%, and 56.60%, respectively. The delayed PLQYs are much larger in CzCbPy and 2CzCbPy than in mCP, which means the RISC process in CzCbPy and 2CzCbPy is more efficient than in mCP. To know the exact RISC efficiency, the rate constant of RISC (k_RISC) was calculated using the reported method.²⁶ The RISC rate is much faster (1.44 × 10⁶ s⁻¹, 1.27 × 10⁶ s⁻¹) in CzCbPy and 2CzCbPy than in mCP (8.79 × 10⁵ s⁻¹). Therefore, it is expected that the TADF characteristic of DMAC-DPS will be better in these two hosts.

Fig. 3 Transient PL decay curves of mCP, CzCbPy, and 2CzCbPy films doped with 20 wt% DMAC-DPS.

Device performances

To evaluate the performances of CzCbPy and 2CzCbPy as host materials for TADF-OLEDs, deep blue TADF-OLEDs with DMAC-DPS were fabricated. The device based on mCP was also fabricated as a reference. The device structures were ITO/1,4,5,8,9,11-hexaazatriphenylene-hexacarbonitrile (HATCN, 7 nm)/4,4′-cyclohexylidenebis[N,N-bis(4-methylphenyl)benzenamine] (TAPC, 40 nm)/3,5-di(9H-carbazol-9-yl)-N,N-diphenylaniline (DCDPA, 10 nm)/host: 20 wt% DMAC-DPS (25 nm)/diphenyl(4-(triphenylsilyl)phenyl)phosphine oxide (TSPO1, 5 nm)/2,2′,2′′-(1,3,5-benzinetriyl)-tris(1-phenyl-1-H-benzimidazole) (TPBi, 30 nm)/LiF (1.5 nm)/Al (100 nm) (Fig. 4). Fig. 5a shows the current density–voltage-luminance curves of the deep blue TADF-OLEDs. The CzCbPy device showed higher current density than the 2CzCbPy device. In addition, both devices showed higher current density than the mCP device due to their bipolar charge transport properties. The luminance was also higher in CzCbPy device (8035 cd m⁻²) than 2CzCbPy and mCP (6624 cd m⁻² and 3181 cd m⁻², respectively) due to the short delayed exciton lifetime and broad exciton recombination zone derived from bipolar characteristic. The current efficiencies of the CzCbPy and 2CzCbPy devices were much higher than that of mCP device (35.0 cd A⁻¹ and 31.3 cd A⁻¹ vs. 24.4 cd A⁻¹) as shown in Fig. 5b. The maximum external quantum efficiency (EQE) of CzCbPy device was 22.9% as shown in Fig. 5c, which is higher than those of 2CzCbPy and mCP devices (18.8% and 17.5%, respectively) and one of the highest efficiency reported so far for deep blue TADF OLED using phosphine oxide-free host. In addition, the CzCbPy device exhibited high EQE of 19.2% even at 1000 cd m⁻², which showed lower efficiency roll-off (16%) than those of 2CzCbPy and mCP devices (23% and 38%, respectively). Such high EQE and low efficiency roll-off of CzCbPy device are due to its higher PLQY (75.90%) and faster RISC rate (1.44 × 10⁶ s⁻¹) than those of 2CzCbPy and mCP devices (72.19% and 1.27 × 10⁶ s⁻¹, 67.32% and 8.79 × 10⁵ s⁻¹, respectively). The faster RISC and bipolar characteristics of CzCbPy and 2CzCbPy reduce triplet-triplet annihilation and exciton-polaron annihilation by transporting holes and electrons to the dopant rapidly and efficiently compared with mCP. As a result, the efficiency roll-off characteristics of CzCbPy and 2CzCbPy devices are better than that of mCP device. To examine the bipolar properties of the two hosts, hole only device (HOD) and electron only device (EOD) with the structures ITO/TAPC (20 nm)/host (50 nm)/TAPC (20 nm)/Al (100 nm) and ITO/TmPyPB (20 nm)/host (50 nm)/TPBi (20 nm)/LiF (1.5 nm)/Al (100 nm), respectively, were fabricated, using common host mCP as a reference. The current densities of 50 mA cm⁻² in the HODs of mCP, CzCbPy, and 2CzCbPy were measured at 10.8 V, 10.1 V, and 13.5 V, respectively, and it was measured in EOD as 14 V, 6.4 V, and 10.8 V, respectively, as shown in Fig. 6. Here the hole current density of HODs with CzCbPy is slightly higher than that of mCP, while that of 2CzCbPy is much lower than those of other hosts. However, in the EODs, all hosts exhibited different electron current density. The CzCbPy shows the highest electron current density, and then 2CzCbPy, followed by mCP. The additional carboline and pyridine units in CzCbPy and 2CzCbPy improved the electron transport property of the hosts. Hence, CzCbPy has the best charge transport property, which can explain that CzCbPy device showed higher efficiency and lower roll-off than 2CzCbPy and mCP devices. By the way, CzCbPy has one less carbazole unit than 2CzCbPy and it was expected that the hole current density of CzCbPy would be less than that of 2CzCbPy. To look into the cause of the better charge transport property of CzCbPy, the molecular packing structures of each host were analysed using polymorph simulation (Fig. 7 and Table 5). The 16 molecules of CzCbPy and 2CzCbPy in packed structure with the lowest energy were selected and the distance between the molecules and the density of each cell were compared. The distance between molecules of CzCbPy (3.92 Å) is closer than that of 2CzCbPy (22.82 Å), which means the order of the molecules and the density of each cell in the former (1.34 g cm⁻³) is much higher than the later (1.27 g cm⁻³). Indeed, as shown in the Fig. 7a, the molecules are well aligned in case of CzCbPy, whereas such type of arrangement is not observed in case of 2CzCbPy (Fig. 7b). This type of molecular arrangement in CzCbPy makes the intermolecular π–π interactions better than in 2CzCbPy, thus faster hole and electron mobility observed in CzCbPy than 2CzCbPy.²⁷ It indicates that CzCbPy has the best charge balance so that the exciton recombination occurs well, resulting in higher efficiency.

Fig. 4 (a) Diagram of the evaluated device structure and energy level of the device. (b) The molecular structures of material for each layer.

Fig. 5 (a) J–V–L characteristics (b) CE-L curves, (c) EQE-L curves, and (d) EL spectra of blue TADF-OLEDs using mCP, CzCbPy and 2CzCbPy with DMAC-DPS.

Fig. 6 J–V characteristics of (a) HOD and (b) EOD of mCP, CzCbPy, and 2CzCbPy.

Fig. 7 Molecular packing simulation results of (a) CzCbPy and (b) 2CzCbPy.

Table 4 Electroluminescence properties of the TADF-OLEDs with new host materials

Hosts	Voltage^a [V]	Voltage^b [V]	Maximum efficiency at 1000 cd m^−2				Efficiency roll-off^e [%]	Max luminance [cd m^−2]	CIE^f [x, y]
			CE^c [cd A^−1]	EQE^d [%]	CE^c [cd A^−1]	EQE^d [%]
a Measured at 1 cd m^−2.b Measured at 1000 cd m^−2.c Current efficiency.d External quantum efficiency.e Ratio from maximum EQE at 1000 cd m^−2.f Measured at 10 mA cm^−2.
mCP	3.3	6.1	24.4	17.5	15.2	10.8	38.3	3181	(0.16, 0.23)
CzCbPy	3.0	5.1	35.0	22.9	29.7	19.8	16.2	8035	(0.15, 0.26)
2CzCbPy	4.0	5.9	31.3	18.8	24.6	14.5	22.9	6624	(0.16, 0.28)

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Table 5 The length of each corner of the cell packed 16 molecules and calculating results of volume and density

Host	A (Å)^a	B (Å)^a	C (Å)^a	Cell volume	Density (g cm^−3)	Distance (Å)^b
a The length of each cell in the x, y, and z axis directions.b The distance between two parallel molecules.
CzCbPy	15.67	34.14	15.19	8126.25	1.34	3.918
2CzCbPy	45.63	12.92	20.43	12044.29	1.26	22.818

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Electroluminescence (EL) spectra and the color coordinates of all devices were shown in Fig. 5d and Table 4. The CzCbPy and 2CzCbPy devices showed slightly red-shifted spectra compared to mCP device. The color coordinates were (0.15, 0.26), (0.16, 0.28), and (0.16, 0.23) for CzCbPy, 2CzCbPy, and mCP devices, respectively. These red-shifts of the color coordinates can be ascribed to the higher polarities of the two hosts compared with mCP and the shift of the recombination zone from the electron transport layer side to the hole transport layer side due to the increased electron mobility of CzCbPy and 2CzCbPy. CzCbPy and 2CzCbPy have high polarity due to their donor–acceptor structures, which serve polar medium to the dopant, resulting in the stabilization of S₁ and the red shift of the spectra as shown in Fig. S4.†

Conclusions

In summary, two δ-carboline-based, phosphine oxide-free host materials were prepared for deep blue TADF OLEDs. The CzCbPy and 2CzCbPy have the same high triplet energy of 3.05 eV and bipolar charge-transport properties. The CzCbPy device doped with DMAC-DPS showed a high quantum efficiency of 22.9% and a small efficiency roll-off of 16%. Such efficiency is one of the highest reported so far in the deep blue TADF OLEDs using phosphine oxide-free host and comparable to that of OLEDs using phosphine oxide based hosts. Evaluation of the lifetime of CzCbPy based device is in progress.

Conflicts of interest

There are no conflicts to declare.

Acknowledgements

This work was supported by Grant No. NRF-2016R1A6A3A11930666 and by the Human Resources Development program (no. 20154010200830) of the Korea Institute of Energy Technology Evaluation and Planning (KETEP) grant funded by the Korea Government Ministry of Trade, Industry and Energy. And this work was also supported by the Industrial Strategic Technology Development Program of MKE/KEIT (10048317).

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Footnotes

† Electronic supplementary information (ESI) available: Synthesis, experimental, DSC and TGA measurement results, cyclic voltammograms measurement, prompt/delayed PL spectra of DMAC-DPS doped 20 wt% in each host. ¹H NMR and ¹³C NMR data. See DOI: 10.1039/c8ra01761a

‡ The manuscripts was written through contributions of all authors. All authors have given approval to the final version of the manuscript. These authors contributed equally. (match statement to author names with a symbol).

§ Present addresses: Department of Information Display, Kyung Hee University, 26, Kyungheedae-ro, Dongdaemoon-gu, Seoul, 02447, Republic of Korea.

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