Issue 40, 2019

A pillar[5]arene with an amino-terminated arm stabilizes the formation of aliphatic hemiaminals and imines

Abstract

We report a new mono-armed pillar[5]arene with the amino-substituent self-included in the pillarene cavity, which can stabilize the hemiaminals and imines formed from the reaction of aliphatic amines and aldehydes as monitored by mass spectroscopy.

Graphical abstract: A pillar[5]arene with an amino-terminated arm stabilizes the formation of aliphatic hemiaminals and imines

Supplementary files

Article information

Article type
Communication
Submitted
10 Mar 2019
Accepted
17 Apr 2019
First published
18 Apr 2019

Chem. Commun., 2019,55, 5736-5739

A pillar[5]arene with an amino-terminated arm stabilizes the formation of aliphatic hemiaminals and imines

X. Du, Q. Jia, C. Wang, K. Meguellati and Y. Yang, Chem. Commun., 2019, 55, 5736 DOI: 10.1039/C9CC01947B

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