Issue 17, 2019
From the journal:

Dalton Transactions

Phosphine-promoted ring-opening of benzisothiazolinate ligands at a nickel(ii) centre: a convenient synthesis of Ni(ii)-thiolate complexes†

Subhi A. Al-Jibori,*a   Samer Hussein Ali,a   Ahmed S. Al-Janabi, ORCID logo b   Christoph Wagnerc  and  Graeme Hogarth ORCID logo *d  

* Corresponding authors

a Department of Chemistry, College of Science, University of Tikrit, Tikrit, Iraq
E-mail: subhi_aljibori@yahoo.com

b Department of Biochemistry, College of Veterinary Medicine, University of Tikrit, Tikrit, Iraq

c Institut für Chemie, Martin-Luther-Universität, Halle-Wittenberg, Kurt-Mothes-Str. 2, D-06120 Halle, Germany

d Department of Chemistry, King's College London, Britannia House, 7 Trinity Street, London SE1 IDB, UK
E-mail: graeme.hogarth@kcl.ac.uk

Abstract

Phosphines react with the benzisothiazolinate (bit) paddlewheel dimer, [Ni2(μ-bit)4·2H2O], resulting in sulfur–nitrogen bond scission and a series of unexpected transformations leading to novel Ni(II) complexes containing 2-cyanophenylthiolate and related thiolate ligands.

Graphical abstract: Phosphine-promoted ring-opening of benzisothiazolinate ligands at a nickel(ii) centre: a convenient synthesis of Ni(ii)-thiolate complexes

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Article information

DOI
https://doi.org/10.1039/C9DT00953A
Article type
Communication
Submitted
04 Mar 2019
Accepted
28 Mar 2019
First published
28 Mar 2019

Dalton Trans., 2019,48, 5520-5522

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Phosphine-promoted ring-opening of benzisothiazolinate ligands at a nickel(II) centre: a convenient synthesis of Ni(II)-thiolate complexes

S. A. Al-Jibori, S. H. Ali, A. S. Al-Janabi, C. Wagner and G. Hogarth, Dalton Trans., 2019, 48, 5520 DOI: 10.1039/C9DT00953A

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