A Cu4L4 metal–organic cage (MOC) composed of amine-protected ligands forms supramolecular coordination polymers (SCPs) upon covalent post-assembly deprotection. The amorphous SCPs form by virtue of aniline–copper coordination and possess a tunable porosity based on the rate of deprotection.
M. L. Schneider, O. M. Linder-Patton and W. M. Bloch, Chem. Commun., 2020, 56, 12969 DOI: 10.1039/D0CC05349J
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