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Abstract | Cited by

Two isostructural MOFs with coordination of different halogen ions (Cl− and Br−), namely NNU-17 and NNU-18, were utilized to reveal the influence of different electron-withdrawing halogen anions on ECR performance. The performance difference between them mainly originates from the different abilities of adsorption and activation of CO2 by halogen ions.

Graphical abstract: Axial Cl/Br atom-mediated CO2 electroreduction performance in a stable porphyrin-based metal–organic framework

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