Issue 25, 2020

Investigation of the slow relaxation of the magnetization dynamics in homoleptic ene-diamido organodysprosium(iii) complexes with K+/arene interactions

Abstract

We report the synthesis, structure and magnetic investigations of two new Dy3+ homoleptic ate-complexes based on different ene-diamido ligands [K(THF)2][Dy(DAD2R)2] (R = H (1), Me (2) DAD2R = [2,6-iPr2C6H3N–CR[double bond, length as m-dash]CR–NC6H3iPr2-2,6] showing K+/arene interactions. Magnetic investigations reval that both compounds exhibit a zero-field single-molecule magnetic relaxation mainly governed by a Raman process.

Graphical abstract: Investigation of the slow relaxation of the magnetization dynamics in homoleptic ene-diamido organodysprosium(iii) complexes with K+/arene interactions

Supplementary files

Article information

Article type
Paper
Submitted
22 Apr 2020
Accepted
03 Jun 2020
First published
04 Jun 2020

CrystEngComm, 2020,22, 4260-4267

Investigation of the slow relaxation of the magnetization dynamics in homoleptic ene-diamido organodysprosium(III) complexes with K+/arene interactions

J. Long, A. O. Tolpygin, A. V. Cherkasov, K. A. Lyssenko, Y. Guari, J. Larionova and A. A. Trifonov, CrystEngComm, 2020, 22, 4260 DOI: 10.1039/D0CE00611D

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