Issue 18, 2020
From the journal:

Organic Chemistry Frontiers

A bench-stable low-molecular-weight vinyl azide surrogate for a cascade reaction: facile access to novel N-vinyl-1,2,3-triazoles†

Zhenhua Liu,a   Lianxiao Wang,a   Tian Yu,a   Yanan Sun, ORCID logo a   Huimin Chen,a   Wen Gao*a  and  Bo Tang ORCID logo *a  

* Corresponding authors

a College of Chemistry, Chemical Engineering and Materials Science, Collaborative Innovation Center of Functionalized Probes for Chemical Imaging in Universities of Shandong, Key Laboratory of Molecular and Nano Probes, Ministry of Education, Shandong Provincial Key Laboratory of Clean Production of Fine Chemicals, Shandong Normal University, Jinan, P. R. China
E-mail: gaowen@sdnu.edu.cn, tangb@sdnu.edu.cn

Abstract

A novel metal-catalyzed cascade reaction of a stable low-molecular-weight vinyl azide surrogate bearing a β-oxygen substituent in a general fashion was disclosed. The orderly insertion of S-/O-nucleophiles and alkynes, for the first time, successfully afforded a diverse range of sulfuryl-substituted N-vinyl-1,2,3-triazoles in good yields.

Graphical abstract: A bench-stable low-molecular-weight vinyl azide surrogate for a cascade reaction: facile access to novel N-vinyl-1,2,3-triazoles

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Article information

DOI
https://doi.org/10.1039/D0QO00714E
Article type
Research Article
Submitted
17 Jun 2020
Accepted
01 Aug 2020
First published
04 Aug 2020

Org. Chem. Front., 2020,7, 2628-2633

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A bench-stable low-molecular-weight vinyl azide surrogate for a cascade reaction: facile access to novel N-vinyl-1,2,3-triazoles

Z. Liu, L. Wang, T. Yu, Y. Sun, H. Chen, W. Gao and B. Tang, Org. Chem. Front., 2020, 7, 2628 DOI: 10.1039/D0QO00714E

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