Open Access Article
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Correction: Structure and solvation of confined water and water–ethanol clusters within microporous Brønsted acids and their effects on ethanol dehydration catalysis
Jason S.
Bates
,
Brandon C.
Bukowski
,
Jeffrey
Greeley
* and
Rajamani
Gounder
*
Charles D. Davidson School of Chemical Engineering, Purdue University, 480 Stadium Mall Drive, West Lafayette, IN 47907, USA. E-mail: jgreeley@purdue.edu; rgounder@purdue.edu
First published on 29th July 2020
Abstract
Correction for ‘Structure and solvation of confined water and water–ethanol clusters within microporous Brønsted acids and their effects on ethanol dehydration catalysis’ by Jason S. Bates et al., Chem. Sci., 2020, 11, 7102–7122, DOI: 10.1039/D0SC02589E.
The authors regret that in the original article there is an error in Fig. 7(a) as it is missing the data set for H-Al-MFI (closed circles). The correct version of Fig. 7 (in which the closed circle data series appears in panel (a)) is presented below.
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Fig. 7 (a) Apparent first-order bimolecular ethanol dehydration rate constant (per H+, 373 K) and (b) activity coefficient ratio (χ = γEWn/γ‡) from eqn (7), as a function of H2O pressure on H-Al-Beta-F(2.0) (■), H-Al-TON (▲), H-Al-FAU (♦), H-Al-MFI (●), H-Al-AEI (□), H-Al-CHA (○), and HPW/Si-MCM-41 ( ). Solid lines in (a) reflect regression of measured rate constants to eqn (7). Inset (a): dependence of k3K2K4−1 values on the largest included sphere diameter of zeolite pores (dLC). Inset (b): slopes of the data sets in (b) in the high water pressure limit, as a function of the channel undulation parameter (dPL/dLC). Solid lines in both insets are to guide the eye. | ||
The Royal Society of Chemistry apologises for these errors and any consequent inconvenience to authors and readers.
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