Issue 40, 2021

Interdigitated Pt–Br chains with π-stacking: an approach toward Robin–Day class I mixed valency in MX-chain complexes

Abstract

The first interdigitated MX-type chain complex with infinite π-stacked arrays was synthesized. The synchronization between a Pt–Br⋯ chain and π-stacking periodicities led to the longest M–X–M distance (6.6978(15) Å) and nil or negligible intervalence charge transfer, which is essential to realize the Robin–Day class I mixed valence state in MX chains.

Graphical abstract: Interdigitated Pt–Br chains with π-stacking: an approach toward Robin–Day class I mixed valency in MX-chain complexes

Supplementary files

Article information

Article type
Communication
Submitted
05 Sep 2021
Accepted
15 Sep 2021
First published
23 Sep 2021

Dalton Trans., 2021,50, 14125-14129

Interdigitated Pt–Br chains with π-stacking: an approach toward Robin–Day class I mixed valency in MX-chain complexes

U. Afrin, K. Fuku, M. Cui, H. Iguchi, M. R. Mian, R. Nakanishi, S. Takaishi and M. Yamashita, Dalton Trans., 2021, 50, 14125 DOI: 10.1039/D1DT02996G

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