Issue 7, 2022

Efficiently increasing low-field magnetic entropy by incorporating SO32− into Gd22Ni21 clusters

Abstract

The distinct nanosized cluster Gd22Ni21 was isolated using a mixture of anions (SO32− and SO42−) as templates, and to the best of our knowledge, this was the first such 3d–4f cluster to have been developed. Additionally, of a number of 3d–4f heterometallic clusters, Gd22Ni21 showed the largest low-field magnetic entropy change (26.1 J kg−1 K−1) at 2.0 K and ΔH = 2.0 T.

Graphical abstract: Efficiently increasing low-field magnetic entropy by incorporating SO32− into Gd22Ni21 clusters

Supplementary files

Article information

Article type
Communication
Submitted
30 Sep 2021
Accepted
24 Jan 2022
First published
25 Jan 2022

Dalton Trans., 2022,51, 2669-2673

Efficiently increasing low-field magnetic entropy by incorporating SO32− into Gd22Ni21 clusters

N. Li, Y. Han, J. Li, Q. Chen and Y. Xu, Dalton Trans., 2022, 51, 2669 DOI: 10.1039/D1DT03314J

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements