Issue 19, 2022

Identification of complexes of Nd(iii) with dithiophosphinic acids verifying the difference in complexation between Ln(iii) and An(iii)

Abstract

Five complex species of Nd(III) with HA have been spectroscopically and compositionally identified as NdA3, NdA3(HA), NdA3(HA)H2O, NdA3(H2O)3, and Nd(H2O)23·3A (HA, bis(2,4,4-trimethylpentyl)dithiophosphinic acid) with the help of X-ray diffraction analysis on single crystals of Nd(H2O)9·H2O·3B (HB = bis(iso-butyl)dithiophosphinic acid.

Graphical abstract: Identification of complexes of Nd(iii) with dithiophosphinic acids verifying the difference in complexation between Ln(iii) and An(iii)

Supplementary files

Article information

Article type
Communication
Submitted
27 Feb 2022
Accepted
29 Mar 2022
First published
02 Apr 2022

Dalton Trans., 2022,51, 7416-7419

Identification of complexes of Nd(III) with dithiophosphinic acids verifying the difference in complexation between Ln(III) and An(III)

Q. Guo, T. Fang, Q. Liu, L. Zhu, S. Yang and G. Tian, Dalton Trans., 2022, 51, 7416 DOI: 10.1039/D2DT00625A

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