NiFe2O4@B,N,F-tridoped CeO2 (NFTDNC): a mesoporous nanocatalyst in the synthesis of pyrazolopyranopyrimidine and 1H-pyrazolo[1,2-b]phthalazine-5,10-dione derivatives and as an adsorbent

Abstract

Mesoporous materials, due to their unique textural and structural features and successful applications in different scientific areas, engrossed our curiosity to form a mesoporous nanostructure. A facile method for the formation of nickel ferrite immobilized over B,N,F tridoped mesoporous cerium oxide (CeO₂) nanostructures (NFTDNC) was designed and communicated in this report. It was characterized by thermogravimetric analysis (TGA), X-ray photoelectron spectroscopy (XPS), powder X-ray diffraction study (PXRD), scanning transmission electron microscopy (STEM), high-resolution transmission electron microscopy (HR-TEM), field emission gun-scanning electron microscopy (FE-SEM), vibrating sample magnetometry (VSM), photoluminescence (PL), Brunauer–Emmett–Teller (BET), energy dispersive X-ray analysis (EDX) and elemental mapping, UV-visible spectroscopy (UV-VIS) and Fourier transform infrared spectroscopy (FT-IR). The applications of the mesoporous nanomaterial (NFTDNC) as an adaptable heterogeneous nanocatalyst and as a phenomenal adsorbent for methyl orange (MO) dye were established. It catalyzed the formation of pyrazolopyranopyrimidine and 1H-pyrazolo[1,2-b]phthalazine-5,10-diones derivatives for the five runs. The recycled catalyst exhibited agglomeration in structural features confirmed by PXRD and HR-TEM studies. NFTDNC as an adsorbent fitted the Freundlich isotherm for the adsorption of MO dye. Moreover, it followed the linear pseudo-second-order kinetics rate equation (R² ≥ 0.98914). MO was adsorbed completely in 60 min with the NFTDNC mesoporous nanostructure.