Oxyanion-modified zero valent iron with excellent pollutant removal performance

Abstract

Oxyanion-modified zero valent iron (OM-ZVI), including oxyanion-modified microscale ZVI (OM-mZVI) and nanoscale zero valent iron (OM-nZVI), has attracted growing interest in recent years for their excellent pollutant removal performance. This feature article summarizes the recent progress of OM-ZVI materials, including their synthesis, characterization, enhanced pollutant removal performance, and structure-property relationships. Generally, OM-ZVI could be synthesized with wet chemical and mechanochemical (ball-milling) methods and then characterized with state-of-the-art characterization techniques (e.g., X-ray-based spectroscopy, electron microscopy) to reveal their structure and physicochemical properties. We found that phosphate modification could form iron-phosphate on the nZVI surface, facilitating Cr(VI) removal, while the phosphorylation process could induce tensile hoop stress to produce numerous radial nanocracks in the structurally-dense spherical nZVI for enhanced Ni(II) removal via a boosted Kirkendall effect. Oxalate modification could trigger electron delocalization to increase electron cloud density and surface-bound Fe(II) of mZVI for enhanced Cr(VI) removal, while oxalated mZVI exhibited more efficient Cr(VI) removal performance via an in situ formed FeC₂O₄·2H₂O shell of high proton conductivity, favoring Cr(VI) reduction. Differently, the mechanochemical treatment of mZVI with B₂O₃ could exert tensile strain on it through interstitial boron doping, thereby promoting the release and transfer of electrons from its Fe(0) core to its iron oxide shell for dramatic Cr(VI) reduction. This article aims to demonstrate the potential of OM-ZVI for pollution control and environmental remediation.