Attila
Kormányos
a,
Balázs
Endrődi
*a,
Zheng
Zhang
a,
Angelika
Samu
a,
László
Mérai
a,
Gergely F.
Samu
ab,
László
Janovák
a and
Csaba
Janáky
*ab
aDepartment of Physical Chemistry and Materials Science, University of Szeged, Aradi sq. 1, Szeged, 6720, Hungary. E-mail: endrodib@chem.u-szeged.hu; janaky@chem.u-szeged.hu
bELI-ALPS, ELI-HU Non-Profit Ltd., Wolfgang Sandner 3, Szeged H-6728, Hungary
First published on 13th March 2023
While CO can already be produced at industrially relevant current densities via CO2 electrolysis, the selective formation of C2+ products seems challenging. CO electrolysis, in principle, can overcome this barrier, hence forming valuable chemicals from CO2 in two steps. Here we demonstrate that a mass-produced, commercially available polymeric pore sealer can be used as a catalyst binder, ensuring high rate and selective CO reduction. We achieved above 70% faradaic efficiency for C2+ products formation at j = 500 mA cm−2 current density. As no specific interaction between the polymer and the CO reactant was found, we attribute the stable and selective operation of the electrolyzer cell to the controlled wetting of the catalyst layer due to the homogeneous polymer coating on the catalyst particles’ surface. These results indicate that sophistically designed surface modifiers are not necessarily required for CO electrolysis, but a simpler alternative can in some cases lead to the same reaction rate, selectivity and energy efficiency; hence the capital costs can be significantly decreased.
Broader contextElectrochemical power-to-gas and power-to-liquid technologies are promising chemical energy conversion approaches to be coupled with intermittent renewable energy sources. As the flagship, the electrochemical production of hydrogen from water electrolysis via PEM electrolyzers has already reached the market. The electrochemical reduction of CO2 builds on this knowledge, and therefore a rapid development of cell structures and cell constituents was witnessed in recent years. Production of CO through CO2 reduction seems to be feasible even at a pilot scale, but the selective production of high-value multi-carbon products is challenging. CO reduction is a possible second step in the cascade electrochemical valorization of CO2, offering a possibility to produce further reduced, higher value products, such as different alcohols, methane, or ethylene. Gas-phase electrolyzers offer a suitable platform for this process, but the low solubility of CO poses notable challenges. This can be tackled by tailoring the microenvironment of the catalyst particles, and thereby high conversion rates and product selectivity could be achieved. |
Two electron products, namely formic acid (formate) and CO can be produced via CO2RR with high selectivity and at a high rate.6–8 Such devices are currently entering the pilot scale and are expected to be industrialized within a decade. The direct production of C2+ products from CO2 is, however, hampered by the low process selectivity. CO is generally accepted to be an intermediate during CO2RR to further reduced products.9 We envision that a two-step electrolysis process (i.e., CO2 → CO → C2 products) can result in higher selectivity and reaction rates, as optimized electrocatalysts and reaction environments can be applied for the two consecutive reaction steps.1 Also, during CO2RR, a large amount of the reactant CO2 is lost due to carbonate formation (with the loss scaling with the e− number used to form a specific product).10 This loss can be only avoided by applying special separators (i.e., bipolar membranes) or electrolyzer cells of special design (e.g., having a liquid layer between two membranes)11 that typically come at a high price in terms of low energy efficiency.12 CO2 loss to the electrolyte solution(s) increases the operating costs of the process, as this has to be recovered from a gas mixture (typically CO2/O2) if high conversions are the focus of the technology. Such an issue is not relevant during CORR, and therefore the reactant loss is minimal in this case.
Since the initial studies on different metal electrodes,13,14 several catalysts were investigated in CORR. Similarly to CO2RR, copper is the only catalyst for C2+ product formation in CORR that shows reasonable performance.2,15–17 This is rooted in the optimal binding energies of the reaction intermediates on copper. The reaction rate and selectivity are also highly dependent on the catalyst morphology and the dominantly available crystal facets, attracting notable attention to catalyst design, such as synthesizing Cu nanocubes, which achieve very high ethylene selectivity in CO2RR.18–20 The mechanism of CORR has been studied via experimental and theoretical means in multiple accounts,21–23 but some uncertainties remain. It is, however, clear from these works that CO adsorption, hydrogenation, and C–C coupling reactions occur at the catalyst surface. Theoretical studies on CO2RR suggest that tri- and tetraalkylammonium groups can promote the reaction by binding certain intermediates.24,25 As CO is a generally considered key intermediate in CO2RR, these studies are relevant for CORR as well. As for CORR, small molecule tetraalkylammonium ions were proved to affect the reaction. Hence, a similar effect of ammonium groups can be envisioned as for CO2RR.26 Furthermore, the promoting effect of alkali cations at the catalyst surface was proved, similarly to the case of CO2RR,27–29 and thus, the presence of these is also necessary for efficient CORR.30 Therefore, beyond the composition and morphology of the catalyst material (with appropriate active site spacing31), its local chemical environment also strongly affects the reaction rate and selectivity. Clearly, CO and a proton source (i.e., H2O) must be simultaneously present at the electrode surface. Notably, the solubility of CO is ca. 30 times lower as compared to that of CO2. Ensuring a short diffusion length (i.e., very thin water layer at the catalyst surface) during CO2RR was shown to be critical for achieving high reaction rates, and that is even more emphasized in the case of CORR.32 In short, a situation as close to the often-mentioned triple-phase boundary conditions as possible should be achieved.
To allow the proper transport of the CO reactant, gas-fed electrolyzer cells must be used, applying gas diffusion electrodes (GDEs).33 In these architectures, the catalyst layer (CL) is immobilized on a hydrophobic porous substrate (gas diffusion layer, GDL) that allows the gas to reach the catalyst surface and ensures the separation of the gas and liquid phases. The CL is in direct contact with a solid (in zero-gap cells) or a liquid electrolyte (in microfluidic electrolyzer cells) from the other side. The composition of the CL influences the reaction zone between the reactant gas (CO in this case), water, and the catalyst nanoparticles, directly affecting the rate and selectivity of the process.34 CLs formed of metal nanoparticles without any additive can be hydrophobic,35 and therefore, CORR can be initially pursued. Under relevant reaction conditions, however, this might change (i.e., because of electrowetting or wetting by the formed products).36 When water enters the CL in large amounts (forming a thick hydration shell around the catalyst particles), it blocks the reactant gas from the catalyst particles, leading to a suddenly increasing HER selectivity.37 Such flooding of the GDE is typically irreversible and is associated with the loss of hydrophobicity of the GDE. As it was demonstrated already for CO2RR, the reaction selectivity gradually decreases, and the parasitic hydrogen evolution reaction (HER) becomes dominant when flooding occurs.38
The surface modification of the catalyst particles with polymeric materials or (large) molecules is an increasingly applied strategy in CO2RR studies, allowing to tune the hydrophobicity of the catalytic surface.39–43 Such polymer materials are most often employed as catalyst binders, immobilized together with the catalyst particles during GDE formation. These include Nafion, other fluorinated polymers, or electrically conducting polymers.44–47 The requirements for a possible binder material are to increase the hydrophobicity of the CL, remain stable under electrolysis conditions, mechanically separate (stabilize) the catalyst nanoparticles, and bind them strongly to the electrode support without blocking the gas transport to the catalyst particles. As a further possible benefit, the binder can also act as a co-catalyst (or reaction promoter) in the reaction by regulating the surface pH,48 changing the surface electronic properties of the catalyst,43 and/or adsorbing/activating the reactant.49 This latter is typically achieved via tailored functional groups (e.g., N-moieties), aiding the adsorption of the reactants and/or intermediates. Interestingly, despite the favorable properties of such additives, their use is much less explored and understood in CORR, compared to CO2RR.
In this contribution, we present that a mass-produced, commercially available pore-sealer fluoropolymer (Capstone ST-110 latex) can act as a catalyst binder, ensuring high rate CORR to C2+ products. We demonstrate that this polymer binder has excellent film-forming ability and, at optimal loadings, covers the surface of the catalyst particles. This ensures that no thick water films form around the catalyst nanoparticles, which would block the path of CO gas. Consequently, hydrogen evolution can be suppressed while acetate, ethanol, ethylene (C2 products), and even propanol form at a high rate.
Continuous-flow electrolysis experiments were performed in a two-electrode setup in a microfluidic cell, designed based on the work of the Kenis research group.50,51 This consisted of stainless steel (1.4571, 316-Ti) electrodes and a poly(methyl methacrylate) (PMMA) separator (d = 2 mm thickness). 3 mm deep, 2 cm × 0.5 cm large cavities were formed on the metal electrodes to serve as gas flow channels. Threaded M5 inlet and outlet connection ports were formed on the cathode for CO transport, while a similar single outlet port was constructed on the anode to allow the evolving O2 to leave the cell. A 2 cm × 0.5 cm large opening was created in the middle of the PMMA separator, defining A = 1 cm2 electrolysis geometric area. ∅ = 1 mm holes were drilled in two opposite sides of this plastic element, going through the middle of the opening, for the transport of the electrolyte solution. The connection of the liquid pump was established by mounting 1 mm needles in the holes. The cathode GDE and the PTFE gasket (d = 100 μm thickness) around it were placed between the cathode electrode and the PMMA separator. The anode was mounted in the cell similarly. CO gas was fed to the cathode in a flow-by mode at a rate of u = 26.5 sccm through a ∅ = 6 mm polyurethane tube (Festo), while an electrolyte solution was directed between the two electrodes through a ∅= 4 mm polyurethane tube (Festo) and the needles mounted in the flow channel at a flow rate of 0.5 cm3 min−1. A Bronkhorst EL-FLOW Select F-201CV mass flow controller and a KF Technology NE-300 syringe pump was used for regulating the gas and the liquid flow rates, respectively.
The electrochemical measurements were controlled using a Biologic VMP300 type instrument. The CORR products were monitored during the electrolysis using a Shimadzu Nexis GC-2030 gas-chromatograph (operated with 6.0 He carrier gas), equipped with a barrier discharge ionization (BID) detector, and an automated 6-way valve injection system. Faradaic efficiency of the CO electrolysis was calculated from the GC results and the measured gas flow rate (Agilent ADM flow meter). Importantly, the pressure increase in the gas line – that could lead to electrode flooding – was avoided by applying a small vacuum pump to fill the sample loop of the injector, sampling the main gas stream.
An atmospheric mass spectrometer (SRS UGA200) was also used to monitor the reaction products and to readily confirm the flooding of the cathode, indicated by the rapid increase in the hydrogen evolution rate. The liquid phase CORR products were quantified using a Bruker AV-III-500-HD NMR instrument after performing a calibration for the studied compounds (with the same background electrolyte concentration as in the real samples). DMSO and phenol were used as internal standards.52
A Thermo Scientific Apreo 2 scanning electron microscope (SEM) was used to collect information on the morphology of the formed electrodes. Top-down and cross-section scanning electron microscopy (SEM) images were recorded with a Thermo Scientific Scios 2 SEM-FIB instrument. A FEI Tecnai G2 20 X-Twin type instrument, operating at an acceleration voltage of 200 kV, was used for recording transmission electron microscopy (TEM) images. An EasyDrop (Krüss) type instrument was used to measure the wetting properties of the different Capstone ST-110 containing GDEs, formed on Freudenberg H23C6 GDLs. A V = 10 μl drop of 1 M KOH solution was formed on the GDE using a syringe with a PTFE lined syringe. Using the CCD camera of the goniometer, the drop contour of the captured photographs was analyzed based on the Young–Laplace equation using the DSA100 software. The contact angles (Θ) were determined as the slope of the contour line at the three-phase contact point. Dynamic contact angle measurements were performed using the same device, first forming a continuously growing droplet (advancing contact angle) and then gradually pulling the liquid back into the syringe (receding contact angle). The gas adsorption properties of Capstone ST-110 films were monitored in quartz crystal microbalance (QCM) experiments using an SRS QCM200 instrument and gold-coated quartz crystal (f0 = 5 MHz). The mass change was calculated from the Sauerbrey equation (Δf = −C × Δm), using a constant value of C = 56.6 Hz μg−1 cm2 as provided in the manual of the instrument.
The morphology of the prepared GDEs was studied by cross-section SEM. To avoid the distortion of the GDE structure (that inevitably happens when a blade is used), a ditch was formed in the GDE by focused ion beam (FIB) technique applying Ga ions. Fig. 1A shows the cross-section SEM image captured from the GDE containing no binder. The thickness of the CL shows notable irregularities in the range of 5–20 μm. This might be due to the absence of the ionomer that might help keeping the nanoparticles in the dispersion and preventing their rapid aggregation. Even if this is the case, it is not reflected in the cross-section image taken from the GDE containing 5 wt% CST (Fig. 1B). The CL appears to be slightly thicker however, the presence of the polymer binder cannot be unequivocally identified (the ion beam used for the cleaning of the freshly etched surface might “burned” the CST at the surface). To better visualize the presence of CST in the CL, top-down SEM images were captured from each Cu/CST GDE with varying CST content (Fig. S1, ESI†). The apparent diameter of the Cu NPs gradually increased with the amount of CST in the CL (5–15 wt%), indicating a polymer shell formation on the nanoparticles. When the CST loading reached 20 wt%, the binder started to form a coherent film on top of the catalyst layer sticking together the Cu NPs. At 30 wt% CST content, almost only the CST film is visible beside a few protruding catalyst nanoparticles.
TEM images (Fig. 1C–E) confirmed the same notion: aggregated Cu NPs (daverage ≈ 12 nm based on TEM images presented in Fig. S2, ESI†) were seen in the absence of the binder, while a thickening polymer layer (a light-grey shell) around the particles was found with the increasing CST concentration. The excess amount of the polymer might penetrate into the pores and/or form a surface film on top of the catalyst layer. We mention here that CST is a commercial pore-sealer material, and therefore this effect is not unexpected. In fact, this motivated our choice of material when we aimed to modify the hydrophilic/hydrophobic nature of our GDE.
CST is a terpolymer of fluorinated alkyl-methacrylates, dialkylammoniumalkyl methacrylate acetate salts, and aliphatic acids, but its exact composition is a trade secret and is therefore not shared with the end-user. An interesting feature, however, is the trialkylammonium group (Fig. S3, ESI,† when protonated), a motif that resembles what is typically present in anion exchange polymers (employed as membranes and ionomers) as well.53,54 Such functional groups were shown to bind CO2, aiding CO2RR, and therefore its participation in the electrolysis process was suggested.55 To reveal any similar interaction between the CST polymer and the CO reactant, quartz crystal microbalance (QCM) experiments were performed (Fig. S4, ESI†). No mass change was detected when Ar or CO gas was purged in the gas chamber over the CST-coated QCM crystal. This shows that the most important role of the CST polymer is not to bind the reactant. Interestingly, a notable mass increase was witnessed when repeating the QCM experiments in CO2 atmosphere. Based on these experiments, no specific contribution of the binder in CORR is expected, while it might assist high-rate CO2RR by binding CO2, thereby increasing its concentration in the immediate vicinity of the catalyst particles.
The hydrophobic/hydrophilic character of freshly prepared GDEs formed of Cu NPs and different amounts of CST were evaluated by contact angle measurements, applying a 1 M KOH solution (Fig. 2A). Here, the binder-free sample was wetted well by the solution (Θ = ∼65°), but a much higher contact angle was measured for all the CST containing GDEs (140 ± 5°), proving the increased hydrophobic character of these layers. We mention that when using pure water as the wetting solution (that is the practice in most studies), no differences were found among the different GDEs, even the CST-free sample was superhydrophobic (with a contact angle above 160°). We note here that surface wetting depends the most on the nature of the solvent, but it can also be affected by the solution pH and the ionic strength (see Fig. S5 for a set of experiments demonstrating this effect, ESI†).
Fig. 2 (A) Contact angles of 1 M KOH droplets at Cu NPs-GDE with varying Capstone content (5–30 wt%). (B) Cell voltage recorded for Cu NPs + 5 wt% CST sample during electrolysis performed at 100–500 mA cm−2 current densities in 1 M KOH electrolyte solution at room temperature. The electrolyte flow rate was 0.5 cm3 min−1, while the CO flow rate was 26.5 sccm. All chronovoltammetric measurements were performed on the same electrode. (C) Product distribution at different current densities with 5 wt% CST containing GDEs. Error bars were calculated from at least two individual measurements. (D) Product distribution was obtained at 300 mA cm−2 current density using Cu NPs-coated GDE with varying CST content. The amount of the formed products were either determined only from the gas outlet stream (left column in each case) or by connecting the gas and liquid outlet stream after a water separator (right column in each case). For further information, see Fig. S10 (ESI†). |
Importantly, even the smallest amount (5 wt%) of CST in the catalyst layer has a huge effect on the selectivity; the amount of H2 decreased while the faradaic efficiency (FE) for ethylene formation increased to 32–37%, along with a notable increase in the amount of the formed liquid C2+ products. The FE for ethanol formation reached 18% at 500 mA cm−2 current density (around 90 mA cm−2 partial current density), while this value was 12% for acetate and around 5.5% for n-propanol, respectively. The measured product distribution is in the range of the best-published examples in the literature using Cu NPs (either commercially available or custom-synthesized) as the cathode catalyst.1,17,57 Interestingly, the product distribution seems to be almost independent of the applied current density, although, based on the approximately 700 mV shift in the cell voltage, it should alter the ratio of the formed CORR products. To scrutinize this behavior further, a small reference electrode was introduced in the electrolyte compartment of the cell (Fig. S9A, ESI†) in the close vicinity of the cathode (∼1 mm distance), and the cathode potential was monitored in parallel with the cell voltage (Fig. S9B, ESI†). Although the uncompensated cathode potential (and hence the cell voltage) changes gradually with the applied current density, the IR-corrected (series resistance values for each applied current density are presented in Table S1, ESI†) cathode potential remains almost constant, the change is less than 50 mV. This very narrow potential regime explains why the product distribution seems identical at the different current densities. We mention that despite this slight difference between the measured cathode potentials, the product distribution slightly depends on the applied current density, for further information, please refer to Table S2 (ESI†).
Selectivity towards C2+ product formation remains similar for the GDEs containing 10 wt% CST and only slightly decreases when the CST content is further increased to 15 wt%. In terms of the total FE (Fig. S10, ESI†), we can account for approximately 85–95% of the passed charge. We assume that the rest of the charge was also consumed by liquid product formation, which, at least in part, was trapped in the GDE. Additionally, the gas outlet of the microfluidic flow cell was coupled to a liquid/gas separation unit (to protect the residual gas analyzer and the GC), adding a buffer to the system. These two factors together lead to a slight underestimation of the amount of the formed products. We also mention that – even though we could not detect – other products might also form during CORR.58
The total FE remained well below 100% when the CST content was increased to values over 15%. It is visible that in some cases, we were only able to account for approximately 25–50% of the passed charge (Fig. S10, ESI†). This phenomenon was accompanied by a notably more vigorous bubble formation in the outlet liquid electrolyte stream as compared to measurements with lower CST content GDEs at identical current densities. Based on this, we assumed that cathodic gas phase products transport to the liquid stream, in this case, instead of exiting the electrolyzer cell with the remnant CO. To determine the composition and the quantity of the gas in the outlet liquid stream, the gas and liquid outlet of the electrolyzer cell was connected downstream of the electrolyzer cell to a liquid/gas separator (for the schematic representation, see Fig. S11, ESI†). This setup allowed us to quantify the formed gas-phase products in the gas and liquid phases together. Almost no additional gas phase products were detected when the CST content remained below 20 wt% (Fig. 2D). On the other hand, if the CST content was higher than that, almost all missing FE was consumed by H2 formation (and this H2 left the cell with the liquid stream). Interestingly, similar results were found for the CLs comprised of the pristine Cu NPs without any additive. While the observed trends for the samples containing a high amount of CST coincide with the one measured for the pristine Cu, we speculate that two separate mechanisms are responsible (Scheme 1). As it was presented in Fig. 2A, Cu NPs (without the addition of any binder) are more hydrophilic in nature when they get in contact with 1 M KOH electrolyte. As a result of this, the GDL gradually gets flooded (even at the lowest applied current density) under electrolysis conditions, resulting in the predominant formation of H2. To gain further insights, dynamic contact angle measurements were performed (Fig. 3A–C). On top of static contact angle values, these measurements provide merit on the infiltration of the electrolyte solution in the GDE over time. This causes hysteresis in the measured contact angles when increasing and subsequently decreasing the volume of the liquid droplet (advancing and receding contact angles, accordingly).
Scheme 1 Schematic structure of the GDE at different binder contents. Without binder, the catalyst layer is flooded (A), as it is also indicated by the contact angle measurements, shown in Fig. 2A. At optimal binder content, the reactant CO reaches the catalyst surface, and the formed products leave the cell with the remnant CO gas (B). At too high binder content, the CO reactant cannot reach the catalyst surface, therefore, H2 evolves at the catalyst/liquid electrolyte interface (C). |
A large hysteresis was seen with the carbon GDL. Such dynamic contact angle measurements were not even possible for the binder-free catalyst layer because the KOH solution almost immediately fully penetrated it. In contrast, almost no hysteresis, hence no notable electrolyte solution penetration was experienced with the CST containing GDEs. To better visualize the electrolyte solution penetration, we formed a V = 500 μl 1 M KOH droplet on a CST-free Cu GDE and a 5% CST-containing Cu GDE and let it penetrate for 10 minutes. Subsequently, the excess liquid was wiped gently, the sample was dried, and FIB-SEM-EDX experiments were performed on the different samples (Fig. 3D and E). These revealed that the CST-free Cu layer was fully impregnated by the electrolyte solution after the 10 minute contact time, while a negligible amount of potassium ions was seen in the 5% CST-containing sample. Note that this measurement directly samples the whole catalyst layer and not only the topmost layer(s).
Therefore, the case of CST-containing GDEs is more complicated. The microenvironment (i.e., hydrophobicity) around the Cu NPs can be effectively tailored by the introduction of CST in the CL. If the CST loading is in the proper range (5–15 wt%), optimal conditions are created, allowing the selective reduction of CO in parallel with suppressed HER. Importantly, CST does not fully cover the surface of the CL, and no coherent layer formation was observed on the SEM images (see Fig. S1, ESI†). Furthermore, contact angles measured for the samples containing CST in 5–15 wt% decreased to the range of what was measured for the Cu NPs without CST after constant current electrolysis performed at j = 300 mA cm−2 (Fig. 2A). This also excludes a coherent film formation on the surface of the CL and suggests that the Cu NPs in the topmost part of the CL are not fully wrapped by the polymer and are accessible for the electrolyte solution. In contrast, a high contact angle and a superhydrophobic character were measured for the electrodes containing at least 20 wt% CST, even after using these in CORR. This is reasoned by the coherent polymer film formation (Fig. S1, ESI†) on the top of the CL, dictating the surface wetting properties. As concluded from the QCM data (Fig. S4, ESI†), the introduction of CST in the CL had no effect on the reactant adsorption. Hence, we attribute only a physical effect to its presence, namely, altering the hydrophobicity at the catalyst/electrolyte interface. Furthermore, the addition of even the smallest amount of CST highly stabilized the CL mechanically, preventing catalyst detachment during electrolysis. The coordination of CST to the Cu catalyst is driven by both a charge compensation and a physical interaction – based on our measurements, a negative ζ-potential was recorded for the dispersed Cu nanoparticles. This is compensated by the CST polymer at ca. 0.15 w% CST content (Fig. S12, ESI†). Above this amount, the CST might adsorb on the catalyst surface by means of physical interaction, and this excess polymer aids the mechanical stability of the formed CL. When a large amount of CST was added, part of the polymer is bound to the surface of the catalyst particles, but some portion was not, the polymer was in excess. According to top-down SEM images, at high CST content, the polymer is present at the surface of the CL, too, forming a coherent layer (Fig. S1, ESI†).
The compact layer formation is in line with the contact angles measured for the 20–30 wt% CST-containing samples after electrolysis (Fig. 2A), showing an unaltered value as compared with the fresh samples. The coherent polymer film formation also explains the larger cell voltages at high CST contents as the electrical resistance of the GDE increases (Fig. S7, ESI†). Similarly, at high polymer content CST might also accumulate at the interface between the GDL and the CL, hindering the gas transport to the CL. The charge still passes, but HER prevails instead of CORR because of the absence of CO in the close vicinity of the catalyst. Based on our detailed FIB SEM studies (Fig. 3D and E) and N2 gas adsorption experiments (not shown here), we could not observe any polymer infiltration in the GDL. Hence the low CORR selectivity at high polymer contents is related to the interfaces between the CL and the solution/GDL, as well as to the structure of the CL. The presence of the polymer binder at the surface of the Cu nanoparticles might also affect the overall pore structure of the catalyst layer. Porosity was shown to influence the CO2RR selectivity of, for example, N-doped nanocarbon electrodes.59 We think that hydrophobicity and pore structure can both have an influence on catalysts selectivity in CORR too.
The performance of the CST-modified samples was compared with binders, widely applied in the literature to tailor the hydrophobicity of the CL.44 We have performed experiments with frequently applied anion exchange ionomers, that ensured high performance in our earlier experiments in zero-gap electrolyzer cells,6,27 but we always experienced the rapid flooding of the cathode GDE. In other experiments, CST was replaced with Nafion, and samples with varying Nafion content (between 5–30 wt%, the same range as in the case of CST) were prepared. A set of chronovoltammetry curves (recorded for the sample containing 5 wt% Nafion) along with the product distribution is presented in Fig. S13 (ESI†). The measured cell voltages are similar to the ones measured for the Cu NPs/CST system, along with the set of the formed products. Importantly, H2 formation was only slightly suppressed in the presence of Nafion compared to the binder-free Cu nanoparticles. Samples prepared with a Nafion content between 5–15 wt% showed the highest selectivity toward CORR. Interestingly, when the Nafion content was above 5 wt%, the C2+ formation rate gradually increased until 4–500 mA cm−2 total current density, where partial current densities suddenly dropped, probably due to the flooding of the GDE (see examples where flooding occurred in Fig. S14, ESI†). Flooding was also confirmed by analyzing the gas products present in the gas and liquid outlet streams of the electrolyzer cell (Fig. S15, ESI,† similar to Fig. 2D), where hydrogen evolution was witnessed almost exclusively at higher current densities. Flooding of the cathode GDE not only manifested in the drop of the cell voltage but it was accompanied by the decrease of the total detected FE values when either Nafion or PTFE or a high amount (above 20 wt%) CST were applied as binders (see the exact values in Table S2, ESI†). As discussed earlier in the manuscript, most of the formed hydrogen in these cases exited the cell with the liquid stream instead of the gas outlet of the cell, hence the observed low total FEs in Fig. 3 and Fig. S15 (ESI†).
A further strategy to increase the hydrophobicity of the CL is the addition of PTFE nanoparticles to the Cu NPs dispersion prior to spray-coating27 or to pre-treat the GDL prior to the immobilization of the CL with a PTFE dispersion.44 In our study, the first approach was used, and no additional binder was applied besides the PTFE NPs (Fig. S16, ESI†). The trends in terms of cell voltages differ from the ones observed in the Nafion- and CST-containing CL cases. While the first experiment at the lowest current density is similar to the other cases, the cell voltage rapidly increases during the second measurement. This is accompanied by the appearance of small dark brown particles in the electrolyte outlet stream, suggesting the mechanical decomposition of the CL during electrolysis. Such degradation was observed for all samples, independent from the PTFE loading. The cell voltage did not change significantly at higher current densities suggesting the excessive formation of H2, while almost no CORR products were detected.
Fig. 4 compares the formation rates of both H2 and all CORR products with and without the different additives at 500 mA cm−2 current density. The amount of formed H2 is similar in the case of the Nafion-, and CST-containing samples, while it is notably higher in the presence of PTFE in the CL. In terms of the CORR products, ethylene was only detected when the CL contained 5 wt% Nafion in the case of the Cu/Nafion system, while more than three times higher partial current densities were obtained with the Cu/CST samples with the optimal CST content (5–10 wt%). This observation underlines that while the addition of Nafion was clearly beneficial to the CORR activity, the GDEs gradually got flooded over the course of the electrolysis (Fig. S14 and S15, ESI†). Similar conclusions can be made regarding the liquid CORR products; the Cu/CST system outperformed its pristine, Cu/Nafion, and Cu/PTFE counterparts.
The stability of the CORR process was monitored for 10 hours at j = 200 mA cm−2 in a 5 M KOH electrolyte solution. As shown in Fig. 5C, the ethylene formation rate (along with the partial current densities for n-propanol and acetate) remained relatively stable within the timeframe of the measurement, with FEs of 32 ± 1%, 10.5 ± 1% and 18.4 ± 0.6% for ethylene, n-propanol, and acetate, respectively. In contrast, partial current densities for ethanol formation decreased from 28 to around 8.3 mA cm−2, while the hydrogen production rate increased from 22 to 66 mA cm−2. We relate this latter effect to the morphological changes of the catalyst particles, distorting the structure of the CL (note the changes in the catalyst morphology on the SEM images in Fig. S17, ESI†), allowing more water to enter the GDE. Such morphological change in copper catalysts is well-known from CO2RR and CORR studies, and therefore it points beyond the scope of our current study. Most importantly, however, no flooding was observed during the measurements, proving the applicability of the Capstone ST-110 as a cathodic catalyst binder for CORR. We note here that the stability depends on a wealth of different parameters (physical degradation of the CL/GDE due to the leaching, restructuring of the catalyst, change of hydrophobicity, precipitation of salts, durability of cell components from the membrane to the current collectors, etc.),60 which must be concurrently optimized to ensure stable long-term operation. In this contribution, the prime focus was on tailoring the wetting properties (i.e., hydrophobic character) of the GDE; the lifetime of the CORR cell could be substantially improved by optimizing these parameters. This is expected to be greatly aided by using sophistically designed catalysts, such as atomically dispersed copper or specifically engineered copper surfaces,61,62 in combination with the presented CST binder.
Footnote |
† Electronic supplementary information (ESI) available. Experimental procedures and results, Fig. S1–S17 and Tables S1, S2. See DOI: https://doi.org/10.1039/d3ey00006k |
This journal is © The Royal Society of Chemistry 2023 |