Designing a new method for growing metal–organic framework (MOF) on MOF: synthesis, characterization and catalytic applications

Abstract

Metal–organic frameworks as a unique class of high-surface-area materials have gained considerable attention due to their characteristic properties. In this perspective, herein, we report an eco-friendly and inexpensive route for the synthesis of 4(3H)-quinazolinones using magnetically separable core–shell-like bimetallic Fe₃O₄-MAA@Co-MOF@Cu-MOF NPs as environmentally-friendly heterogeneous catalysts. To the best of our knowledge, this is the first example of the integration of two different types of MOFs, which contain two different metal ions (Co²⁺ in the core and Cu²⁺ in the shell) using an external ligand. Our study not only introduces a novel nanostructured catalyst for the organic reaction but also presents a new strategy for the combination of two MOFs in one particle at the nanometer level. To survey the structural and compositional features of the synthesized nanocatalyst, a variety of spectroscopic and microscopic techniques including FT-IR, XRD, BET, TEM, HR-TEM, FE-SEM, EDX, EDX-mapping, TGA, VSM, and ICP-OES were employed. The combination of magnetic Co-MOF with Cu-MOF leads to achieving unique structural and compositional properties for Fe₃O₄-MAA@Co-MOF@Cu-MOF NPs with a particle size of 20–70 nm, mesostructure, and relatively large specific surface area (236.16 m² g⁻¹). The as-prepared nanostructured catalyst can be an excellent environment catalyst for the synthesis of a wide library of 4(3H)-quinazolinones derivatives, including electron-donating and electron-withdrawing aromatic, heteroaromatic, and aliphatic compounds under solvent-free conditions much better than the parent precursors. Moreover, by investigating the longevity of the nanocatalyst, the conclusion could be derived that the aforesaid nanocatalyst is stable under reaction conditions and could be recycled for at least seven recycle runs without a discernible decrease in its catalytic activity.