Ready-to-be-addressed oxo-clusters: individualized, periodically organized and separated from the substrate

Juba Salhi; Jan Patrick Calupitan; Michele Mattera; David Montero; Antoine Miche; Régina Maruchenko; Anna Proust; Guillaume Izzet; David Kreher; Imad Arfaoui; Florence Volatron

doi:10.1039/D3NR02649C

Ready-to-be-addressed oxo-clusters: individualized, periodically organized and separated from the substrate†

Juba Salhi,^a Jan Patrick Calupitan,

^a Michele Mattera,^a David Montero,^b Antoine Miche,^c Régina Maruchenko,^a Anna Proust,

^a Guillaume Izzet,

^a David Kreher,^d Imad Arfaoui^e and Florence Volatron

*^a

Author affiliations

* Corresponding authors

^a Institut parisien de chimie moléculaire (IPCM), CNRS, Sorbonne Université, 4 Place Jussieu, F-75005 Paris, France
E-mail: florence.volatron@sorbonne-universite.fr

^b Fédération de chimie et matériaux de Paris-centre (FCMat), Sorbonne Université, 4 Place Jussieu, F-75005 Paris, France

^c Laboratoire de réactivité de surface (LRS), CNRS, Sorbonne Université, 4 Place Jussieu, F-75005 Paris, France

^d Institut Lavoisier de Versailles (ILV), CNRS, Université Paris-Saclay, 45 avenue des Etats-Unis, F-78035 Versailles, France

^e De la molécule aux nano-objets: réactivité, interactions et spectroscopies (MONARIS), CNRS, Sorbonne Université, 4 Place Jussieu, F-75005 Paris, France

Abstract

Clusters and oxo-clusters are drawing attention for their amazing physical properties, especially at the scale of the single molecule. However, chemical methods to organize them individually on a surface are still lacking. In this study we show that it is possible to periodically organize individual polyoxometalates thanks to their ordering by a new supramolecular assembly.

Nanoscale

Ready-to-be-addressed oxo-clusters: individualized, periodically organized and separated from the substrate†

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Ready-to-be-addressed oxo-clusters: individualized, periodically organized and separated from the substrate

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