Issue 13, 2023

Carbamate thermal decarboxylation for the design of non-isocyanate polyurethane foams

Abstract

Polyurethane foams remain at the forefront of cushioning, insulation, packaging, and structural applications. Risk of exposure to isocyanate-containing precursors during foaming operations directly contributes to the regulation of isocyanates, thus prompting investigations into non-isocyanate alternatives. This work presents non-isocyanate polyurethanes (NIPUs) that are readily prepared from carbonyldiimidazole (CDI) derived monomers for efficient synthetic methods that strive to adhere to the principles of green chemistry. Various bis-carbonylimidazolide (BCI) monomers undergo β-hydrogen elimination at temperatures exceeding 140 °C, which liberates a carbamic acid that subsequently decarboxylates. Decarboxylation provides an in situ blowing agent, and carbon dioxide is capable of producing a microcellular foam with concurrent crosslinking. BCI difunctional monomers in presence of trifunctional crosslinking agents enabled the synthesis of both rigid and flexible NIPU foams, and the addition of conventional surfactants and catalysts allowed for precise control over pore structure. Thermomechanical analysis elucidated foam glass transition temperatures ranging from 0 to 120 °C and coefficients of thermal expansion on the order of 10−6 mm mm−1 °C. Scanning electron microscopy enabled characterization of pore size and foam structure. Optimized catalyst and surfactant levels enabled a range of flexible and rigid foam compositions. Fundamental structure–property-processing relationships were established for novel BCI-derived NIPU foams to reliably predict performance.

Graphical abstract: Carbamate thermal decarboxylation for the design of non-isocyanate polyurethane foams

Supplementary files

Article information

Article type
Paper
Submitted
29 Jan 2023
Accepted
01 Mar 2023
First published
03 Mar 2023

Polym. Chem., 2023,14, 1497-1506

Carbamate thermal decarboxylation for the design of non-isocyanate polyurethane foams

J. I. Sintas, J. D. Wolfgang and T. E. Long, Polym. Chem., 2023, 14, 1497 DOI: 10.1039/D3PY00096F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements