Chiral photonic crystals from sphere packing

Abstract

Inspired by recent developments in self-assembled chiral nanostructures, we have explored the possibility of using spherical particles packed in cylinders as building blocks for chiral photonic crystals. In particular, we focused on an array of parallel cylinders arranged in a perfect triangular lattice, each containing an identical densest sphere packing structure. Despite the non-chirality of both the spheres and cylinders, the self-assembled system can exhibit chirality due to spontaneous symmetry breaking during the assembly process. We have investigated the circular dichroism effects of the system and have found that, for both perfect electric conductor and dielectric spheres, the system can display dual-polarization photonic band gaps for circularly polarized light at normal incidence along the axis of the helix. We have also examined how the polarization band gap size depends on the dielectric constant of the spheres and the packing fraction of the cylinders. Furthermore, we have explored the effects of non-ideality and found that the polarization gap persists even in the presence of imperfections and heterogeneity. Our study suggests that a cluster formed by spheres self-assembling inside parallel cylinders with appropriate material parameters can be a promising approach to creating chiral photonic crystals.