Issue 18, 2024

The low loading of metal in metal–organic framework-derived NiNx@NC promotes amide formation through C–N coupling

Abstract

The pyrolysis of Ni-substituted zeolitic imidazolate framework-8 produces NiNx@NC with an ultra-low loading of Ni (7.4 × 10−6 mol%). The Ni–N coordination, subnanometer particle size, and uniform distribution of NiNx on the NC support lead to excellent catalytic activity (TON = 2702) and selectivity for the amination of aldehydes to produce amides.

Graphical abstract: The low loading of metal in metal–organic framework-derived NiNx@NC promotes amide formation through C–N coupling

Supplementary files

Article information

Article type
Communication
Submitted
08 Dec 2023
Accepted
01 Feb 2024
First published
01 Feb 2024

Chem. Commun., 2024,60, 2544-2547

The low loading of metal in metal–organic framework-derived NiNx@NC promotes amide formation through C–N coupling

V. Vyas, V. Kumar and A. Indra, Chem. Commun., 2024, 60, 2544 DOI: 10.1039/D3CC06002K

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements