Metalloporphyrinic metal–organic frameworks for enhanced photocatalytic degradation of a mustard gas simulant

Alisa S. Quon; Doroteo Manriquez; Anna Nguyen; Edgar K. Papazyan; Pavithra Wijeratne; Lun An; Long Qi; Matthew J. Tang; Austin D. Ready; Omar K. Farha; Yangyang Liu

doi:10.1039/D4CC03890H

Metalloporphyrinic metal–organic frameworks for enhanced photocatalytic degradation of a mustard gas simulant†

Alisa S. Quon,

‡^a Doroteo Manriquez,‡^a Anna Nguyen,§^a Edgar K. Papazyan,§^a Pavithra Wijeratne,^a Lun An,^b Long Qi,

^b Matthew J. Tang,^a Austin D. Ready,^c Omar K. Farha*^d and Yangyang Liu

*^a

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* Corresponding authors

^a Department of Chemistry and Biochemistry, California State University, Los Angeles, 5151 State University Drive, Los Angeles, California 90032, USA
E-mail: yliu114@calstatela.edu

^b U.S. DOE Ames National Laboratory, Iowa State University, Ames, Iowa 50011, USA

^c Department of Chemistry and Biochemistry, University of California, Los Angeles, 607 Charles E. Young Drive East, Los Angeles, California 90095, USA

^d Department of Chemistry and International Institute for Nanotechnology (IIN) and Department of Chemical & Biological Engineering, Northwestern University, Evanston, Illinois 60208, USA
E-mail: o-farha@northwestern.edu

Abstract

Four metalloporphyrinic metal–organic frameworks (MOFs) were successfully synthesized and exhibited enhanced activities for the photooxidation of a sulfur mustard simulant, 2-chloroethyl ethyl sulfide (CEES). Among them, a Sn-porphyrin functionalized 2D MOF, namely CSLA-21-NH₂(Sn), showed a half-life of 1.5 min for CEES oxidation under blue LED, featuring as one of the fastest photocatalysts for CEES degradation.

This article is part of the themed collection: Emerging Trends in MOFs

Chemical Communications

Metalloporphyrinic metal–organic frameworks for enhanced photocatalytic degradation of a mustard gas simulant†

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Metalloporphyrinic metal–organic frameworks for enhanced photocatalytic degradation of a mustard gas simulant

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