Issue 13, 2025
From the journal:

Chemical Communications

Zirconium vs. hafnium: a comparative study of mesoporous MOF stability†

Orysia Zaremba,a   Subhajit Dutta, ORCID logo a   Jesus Requies, ORCID logo b   Jacopo Andreo ORCID logo a  and  Stefan Wuttke ORCID logo *ac  

* Corresponding authors

a BCMaterials, Basque Center for Materials, UPV/EHU Science Park, Leioa 48940, Spain
E-mail: stefan.wuttke@bcmaterials.net

b School of Engineering (UPV/EHU), Plaza Ingeniero Torres Quevedo 1, 48013 Bilbao, Spain

c United Arab Emirates University, PO Box 15551, Al Ain, Abu Dhabi, United Arab Emirates

Abstract

A wide range of mesoporous Zr and Hf metal–organic frameworks (MOFs), namely MIP-206, MOF-808, and NU-1000, as well as the microporous UiO-66, were systematically investigated and compared in terms of thermal and chemical stability. The holistic effects of metal type (Zr vs. Hf), linker type (small and rigid vs. large and flexible), and framework topology (2D vs. 3D) on the overall framework stability were investigated.

Graphical abstract: Zirconium vs. hafnium: a comparative study of mesoporous MOF stability

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Article information

DOI
https://doi.org/10.1039/D4CC03103B
Article type
Communication
Submitted
25 Jun 2024
Accepted
19 Dec 2024
First published
08 Jan 2025

Chem. Commun., 2025,61, 2794-2797

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Zirconium vs. hafnium: a comparative study of mesoporous MOF stability

O. Zaremba, S. Dutta, J. Requies, J. Andreo and S. Wuttke, Chem. Commun., 2025, 61, 2794 DOI: 10.1039/D4CC03103B

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