A HF-resistant perfluorinated porous polymer for the separation of electronic specialty gases†
Abstract
A perfluorinated porous polymer, PFPP-1, featuring large SBET (1068 m2 g−1) and ultrahigh fluorine content (35.6 at%), was synthesized to accomplish high HF resistance and selective adsorption of F-gases. Enhanced dipole interactions and optimal F-gas/N2 selectivity highlight PFPP-1's potential for efficient recovery of electronic specialty gases in sustainable electronics.