We report on the emissive properties of two related bismuth complexes, LBiBr2 and LBi, with a monoanionic 2,6-diiminophenyl N,C,N pincer ligand L. The Bi(III) complex phosphoresces at 77 K, while the bismuthinidene Bi(I) species represents the first example of a phosphorescent bismuth complex that emits in the near infrared at room temperature.
K. L. Deuter, D. J. J. Balaba, M. Linseis and R. F. Winter, Chem. Commun., 2025, 61, 3548 DOI: 10.1039/D5CC00127G
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