High-modulus supramolecular glassy polymers: a review

Abstract

Supramolecular glassy polymers are innovative and versatile materials. Their tunable mechanical properties and sustainability have become the focus of current research. This review presents recent research on high-modulus and high-performance supramolecular glassy polymers, emphasizing the importance of using supramolecular bonding (non-covalent bonding) in design strategies to enhance material properties. In addition, the paper explores the cyclic utilization as well as self-healing capabilities of these polymers through non-covalent bonding and looks into the potential applications of supramolecular glassy polymers. Finally, the paper presents the current opportunities and major challenges in developing supramolecular glassy polymers, providing new ideas for high-performance materials.