Issue 5, 2025

An integrated strategy for corncob pretreatment and coproduction of furfural and monosaccharides based on p-toluenesulfonic acid and a deep eutectic solvent system

Abstract

High-value valorization of cellulose and hemicellulose fractions in lignocellulosic biomass is crucial for a feasible biomass refinery scheme. In this study, an integrated strategy was developed for pretreatment of corncob and coproduction of furfural and high-concentration fermentable sugars. The hemicellulose fraction in raw corncob was selectively extracted to produce a xylose-rich hydrolysate via pretreatment with dilute p-toluenesulfonic acid (p-TsOH) under optimal reaction conditions (0.5% p-TsOH, 160 °C, and 30 min). Thereafter, the xylose hydrolysate was subjected to catalytic conversion in a DES (TEBAC : LA = 1 : 4) system at 190 °C for 10 min. Notably, 78.6% furfural yield was achieved, and the corresponding xylose conversion was close to 100.0%. In addition, the pretreated corncob residue exhibited excellent enzymatic digestibility as the yields of reducing sugar and glucose were 90.7% and 97.0%, respectively, at a high solid loading of 12%. This proposed approach represents an integrated strategy for coproduction of multiple products from agriculture residues.

Graphical abstract: An integrated strategy for corncob pretreatment and coproduction of furfural and monosaccharides based on p-toluenesulfonic acid and a deep eutectic solvent system

Supplementary files

Article information

Article type
Paper
Submitted
15 Oct 2024
Accepted
30 Jan 2025
First published
31 Jan 2025

React. Chem. Eng., 2025,10, 1096-1107

An integrated strategy for corncob pretreatment and coproduction of furfural and monosaccharides based on p-toluenesulfonic acid and a deep eutectic solvent system

L. Luo, W. Wu, Y. Shen, Y. Tao, L. Wang and Q. Qing, React. Chem. Eng., 2025, 10, 1096 DOI: 10.1039/D4RE00500G

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