The rate equation for the reaction of N-methyl-N-nitrosoaniline in aqueous hydrochloric acid is v=k[PhNMeNO]h01.17; this, together with the observed isotope effects and rate measurements in the presence of added N-methylaniline is inconsistent with the commonly accepted mechanism and shows that the rearrangement is intramolecular and takes place concurrently with reversible denitrosation.
T. D. B. Morgan and D. L. H. Williams, J. Chem. Soc. D, 1970, 1671 DOI: 10.1039/C29700001671
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