Direct measurement of enantiomerization of labile aluminium(III)β-diketonates
Abstract
Dynamic n.m.r. studies of tris-(2,6-dimethylheptane-3,5-dionato)aluminium(III), and bis(pentane-2,4-dionato)-(2,6-dimethylheptane-3,5-dionato)aluminium(III) give proof of the rapid enantiomerization of these complexes.