The retention of configuration of the migrating benzylic group in a photochemical 1,3-allylic shift is demonstrated in the rearrangement of 3-methyl-5-phenyl-dicyanomethylenecyclohexane to 2,2-dicyano-5-methyl-3-phenylmethylenecyclohexane.
R. C. Cookson, J. Hudec and M. Sharma, J. Chem. Soc. D, 1971, 107 DOI: 10.1039/C29710000107
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