Dichlorotris(triphenylarsine)ruthenium(II), dissolved in benzene, readily activates molecular O2, H2, CO, and olefins to give new catalytic species of importance in homogeneous catalysis; the oxygen complex is the first known example of a 1 : 1 paramagentic complex of a d6 metal ion.
M. M. T. Khan, R. K. Andal and P. T. Manoharan, J. Chem. Soc. D, 1971, 561 DOI: 10.1039/C29710000561
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