Issue 3, 1972
From the journal:

Journal of the Chemical Society, Dalton Transactions

Complexes of molybdenum and tungsten chlorides

D. G. Blight,   D. L. Kepert,   R. Mandyczewsky  and  K. R. Trigwell  

Abstract

Six-co-ordinate complexes of the type WCl4(ligand)2 and WCl4(bidentate) and the apparently seven-co-ordinate [WCl4(Me3N)3] have been obtained from [WCl4(RCN)2] under mild conditions. Reduction to polymeric tungsten(III) compounds occurs under more vigorous conditions. The bidentate o-phenylenebisdimethylarsine forms a number of complexes, including the seven-co-ordinate [WCl5(diars)] and [WOCl4(diars)]. However no evidence for eight-co-ordinate [MCl4(diars)2] or [MCl4(diars)2]+(where M is Mo or W) could be obtained.

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Article information

DOI
https://doi.org/10.1039/DT9720000313
Article type
Paper

J. Chem. Soc., Dalton Trans., 1972, 313-316

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Complexes of molybdenum and tungsten chlorides

D. G. Blight, D. L. Kepert, R. Mandyczewsky and K. R. Trigwell, J. Chem. Soc., Dalton Trans., 1972, 313 DOI: 10.1039/DT9720000313

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