Arrhenius parameters are reported for the thermal isomerisation of hexa-1,trans-3,5-triene to the cis-compound and for the unimolecular decomposition of cyclohexa-1,3-diene to benzene and hydrogen which is symmetry-forbidden as a direct concerted process and proceeds via cyclohexa-1,4-diene.
S. W. Orchard and B. A. Thrush, J. Chem. Soc., Chem. Commun., 1973, 14 DOI: 10.1039/C39730000014
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