Issue 4, 1973
From the journal:

Journal of the Chemical Society, Chemical Communications

Formation of 1,4-anhydropyranoses from 1-O-acetyl-6-deoxy-2,3-O-isopropylidene-4-O-methylsulphonyl-α-L-manno- and talo-pyranose

John S. Brimacombe,   Johnathan Minshall  and  Leslie C. N. Tucker  

Abstract

1-O-Acetyl-6-deoxy-2,3-O-isopropylidene-4-O-methylsulphonyl-α-L-mannopyranose (3) and the epimeric L-talopyranose derivative (4) yield the 1,4-anhydropyranoses (7) and (8), respectively, on treatment with sodium azide in hot NN-dimethylformamide; a possible general mechanism is suggested for these and related reactions.

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Article information

DOI
https://doi.org/10.1039/C39730000142
Article type
Paper

J. Chem. Soc., Chem. Commun., 1973, 142-143

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Formation of 1,4-anhydropyranoses from 1-O-acetyl-6-deoxy-2,3-O-isopropylidene-4-O-methylsulphonyl-α-L-manno- and talo-pyranose

J. S. Brimacombe, J. Minshall and L. C. N. Tucker, J. Chem. Soc., Chem. Commun., 1973, 142 DOI: 10.1039/C39730000142

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