The reductoisomerase of Salmonella typhimurium has a requirement for the 2S-isomer of acetolactate (III, R = Me) while the αβ-dihydroxy-acid dehydratase has a requirement for the 2R configuration but is not stereoselective with respect to the configuration at C-3.
F. B. Armstrong, C. J. R. Hedgecock, J. B. Reary, D. Whitehouse and D. H. G. Crout, J. Chem. Soc., Chem. Commun., 1974, 351 DOI: 10.1039/C39740000351
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