Acyloxycarbenes are generated by thermal fragmentation of 5-benzoyloxy-1,3-dioxan-4,6-diones (1 and 2) and by thermal α-elimination of benzoic acid from 3-benzoyloxyphthalide (6).
R. F. C. Brown, F. W. Eastwood and G. L. McMullen, J. Chem. Soc., Chem. Commun., 1975, 328 DOI: 10.1039/C39750000328
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