The perturbation of the ligands by the metal ion, in contrast to the converse procedure of traditional crystal field theory, accounts satisfactory for the relatively strong d-electron absorption bands of the tetrahedral transition-metal tetrahalides.
R. Gale, R. E. Godfrey, S. F. Mason, R. D. Peacock and B. Stewart, J. Chem. Soc., Chem. Commun., 1975, 329 DOI: 10.1039/C39750000329
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