The influence of added water on the kinetics of formation of the mono-nickel(II) pyridine 2-azodimethyl-aniline complex in acetonitrile is reported; complex changes in the activation parameters suggest that the solvent can induce a change of reaction mechanism.
H. P. Bennetto and Z. S. Imani, J. Chem. Soc., Chem. Commun., 1975, 333 DOI: 10.1039/C39750000333
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