Issue 23, 1975

The temperature dependence of some physical properties of cobinamides and cobalamins

Abstract

The temperature dependences of the electronic absorption spectra and the 1H n.m.r. spectra of the cobinamides and cobalamins are discussed. A conformational change, which does not involve the removal of the 5,6-dimethyl-benzimidazole ligand from the co-ordination sphere of the cobalt is favoured as an explanation of the temperature dependence of these physical properties of the cobalamins.

Article information

Article type
Paper

J. Chem. Soc., Dalton Trans., 1975, 2633-2634

The temperature dependence of some physical properties of cobinamides and cobalamins

S. A. Cockle, O. D. Hensens, H. A. O. Hill and R. J. P. Williams, J. Chem. Soc., Dalton Trans., 1975, 2633 DOI: 10.1039/DT9750002633

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