Treatment of isopimaran-8β-ol and derivatives with ‘long-range’ oxidants has resulted in functionalization of the 10β- and 4β-methyl groups but not of the 13β-methyl group. Similar oxidation of hopan-7α-ol and hopan-15β-ol and their 21αH-epimers has led to functionalization of the 14α-, 18α-, and 8β-methyl groups.
R. E. Corbett and A. L. Wilkins, J. Chem. Soc., Perkin Trans. 1, 1975, 710 DOI: 10.1039/P19750000710
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