Issue 19, 1976
From the journal:

Journal of the Chemical Society, Chemical Communications

New synthetic route to mono-η5-cyclopentadienylmolylbdenum compounds: X-ray crystal structure of [(η-C5H5)Mo(Ph2PCH2CH2PPh2)(η-C6H8)][PF6]·SO2

John A. Segal,   Malcolm L. H. Green,   Jean-Claude Daran  and  Keith Prout  

Abstract

The compound [(η5-C5H5)Mo(η6-C6H6)Cl]is shown to be a versatile precursor for carbonyl-free monocyclopentadienylmolybdenum derivatives and the new compounds [(η5-C5H5)Mo(dppe)L2][PF6](L2= dppe, (MeCN)2, C4H6, η4-C8H8, Ph2C2, or Me2C2), [(η5-C5H5)Mo(η8-C8H8)][PF6], [η5-C5H5)Mo(η6-C8H8)L][PF6](L = PPh3 or CO), and [(η5-C5H5)Mo(dppe)(C6H8)][PF6] are described (dppe = Ph2PCH2CH2PPh2); the crystal structure of the last compound has been determined.

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Article information

DOI
https://doi.org/10.1039/C39760000766
Article type
Paper

J. Chem. Soc., Chem. Commun., 1976, 766-768

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New synthetic route to mono-η5-cyclopentadienylmolylbdenum compounds: X-ray crystal structure of [(η-C5H5)Mo(Ph2PCH2CH2PPh2)(η-C6H8)][PF6]·SO2

J. A. Segal, M. L. H. Green, J. Daran and K. Prout, J. Chem. Soc., Chem. Commun., 1976, 766 DOI: 10.1039/C39760000766

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