In the thermal decarbonylation of cage ketones of type (1), the presence of an oxygen-containing bridge or a hydroxy-substituent resulted in an unusual rearrangement and cleavage reaction, e.g. the conversions of (1e) into (3) and (4) into (5).
Y. Yamashita, T. Mukai and T. Tezuka, J. Chem. Soc., Chem. Commun., 1977, 532 DOI: 10.1039/C39770000532
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