Treatment of 2′,3′,5′-tri-O-acetyl-5-iodouridine and 3′,5′-di-O-acetyl-5-iododeoxyuridine with trifluoromethyl iodide and copper powder gave the corresponding 5-trifluoromethyluridine derivatives; this is the first example of direct trifluoromethylation of nucleosides.
Y. Kobayashi, I. Kumadaki and K. Yamamoto, J. Chem. Soc., Chem. Commun., 1977, 536 DOI: 10.1039/C39770000536
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