The photochemically induced valence isomerization of α-diazocarbonyl compounds to give diazirines which had previously been pointed out to be restricted to α-diazo-amides has now been observed in the α-diazoketones (1) and (5).
T. Miyashi, T. Nakajo and T. Mukai, J. Chem. Soc., Chem. Commun., 1978, 442 DOI: 10.1039/C39780000442
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