Absorbance difference measurements and chromatographic analyses indicate that bilirubin-IXα and its dimethyl ester rapidly form less stable, more polar (5E,15Z), (5Z,15E), and (5E,15E)-configurational isomers on irradiation with visible light.
A. F. McDonagh, D. A. Lightner and T. A. Wooldridge, J. Chem. Soc., Chem. Commun., 1979, 110 DOI: 10.1039/C39790000110
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